A new bimetallic ferrimagnet ([Mn2II(H2O)2(CH3COO)][MoV(CN)8]•2H2O)n and its antiferromagnetic analogue ([Mn2II(H2O)3Cl][MoV(CN)8]•4H2O)n

被引：24
|
作者：
Ma, Shu-Lin [1 ]
Ma, Yue [1 ]
Ren, Shi [1 ]
Yan, Shi-Ping [1 ]
Cheng, Peng [1 ]
Wang, Qing-Lun [1 ]
Liao, Dai-Zheng [1 ]
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
来源：
CRYSTAL GROWTH & DESIGN | 2008年 / 8卷 / 10期
基金：
中国国家自然科学基金;
关键词：
D O I：
10.1021/cg800392a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction between Cs-3[Mo(CN)(8)]center dot 2H(2)O and MnCl2 center dot 4H(2)O gives two new cyano-bridged bimetallic compounds of ([Mn-2(II)(H2O)(2)(CH3COO)][Mo-V(CN)(8)]center dot 2H(2)O)(n) (1) and ([Mn-2(II)(H2O)(3)C][Mo-V(CN)(8)]center dot 4H(2)O)(n) (2) in different conditions. The magnetic behaviors of these complexes have been investigated, indicating that 1 is a ferrimagnet with an ordering temperature of about 6 K and that for 2 there is antiferromagnetic coupling between the paramagnetic ions in the system.
引用
收藏
页码：3761 / 3765
页数：5
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