A new bimetallic ferrimagnet ([Mn2II(H2O)2(CH3COO)][MoV(CN)8]•2H2O)n and its antiferromagnetic analogue ([Mn2II(H2O)3Cl][MoV(CN)8]•4H2O)n

被引：24

作者：

Ma, Shu-Lin ^{[1
]}

Ma, Yue ^{[1
]}

Ren, Shi ^{[1
]}

Yan, Shi-Ping ^{[1
]}

Cheng, Peng ^{[1
]}

Wang, Qing-Lun ^{[1
]}

Liao, Dai-Zheng ^{[1
]}

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2008年 / 8卷 / 10期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1021/cg800392a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction between Cs-3[Mo(CN)(8)]center dot 2H(2)O and MnCl2 center dot 4H(2)O gives two new cyano-bridged bimetallic compounds of ([Mn-2(II)(H2O)(2)(CH3COO)][Mo-V(CN)(8)]center dot 2H(2)O)(n) (1) and ([Mn-2(II)(H2O)(3)C][Mo-V(CN)(8)]center dot 4H(2)O)(n) (2) in different conditions. The magnetic behaviors of these complexes have been investigated, indicating that 1 is a ferrimagnet with an ordering temperature of about 6 K and that for 2 there is antiferromagnetic coupling between the paramagnetic ions in the system.

引用

页码：3761 / 3765

页数：5

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