Low-Cost High-Performance Zinc Antimonide Thin Films for Thermoelectric Applications

被引：60

作者：

Sun, Ye ^{[1
,2
]}

Christensen, Mogens ^{[1
,2
]}

Johnsen, Simon ^{[1
,2
]}

Nong, Ngo V. ^{[3
]}

Ma, Yi ^{[4
]}

Sillassen, Michael ^{[2
,5
]}

Zhang, Eryun ^{[2
,5
]}

Palmqvist, Anders E. C. ^{[4
]}

Bottiger, Jorgen ^{[2
,5
]}

Iversen, Bo B. ^{[1
,2
]}

机构：

[1] Aarhus Univ, Dept Chem, Ctr Mat Crystallog, DK-8000 Aarhus C, Denmark

[2] Aarhus Univ, INANO, DK-8000 Aarhus C, Denmark

[3] Tech Univ Denmark, Riso Natl Lab Sustainable Energy, Fuel Cells & Solid State Chem Div, DK-4000 Roskilde, Denmark

[4] Chalmers Univ Technol, Dept Chem & Biol Engn, SE-41296 Gothenburg, Sweden

[5] Aarhus Univ, Dept Phys, DK-8000 Aarhus C, Denmark

来源：

ADVANCED MATERIALS | 2012年 / 24卷 / 13期

基金：

新加坡国家研究基金会;

关键词：

thermoelectrics; thin films; magnetron sputtering; zinc antimonide; thermal stability; PHONON-GLASS; ZN4SB3;

D O I：

10.1002/adma.201104947

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Zinc antimonide thin films with high thermoelectric performance are produced by a simple sputtering method. The phase-pure Zn4Sb3 and ZnSb thin films fulfill the key requirements for commercial TE power generation: cheap elements, cheap fabrication method, high performance and thermal stability. In addition, two completely new meta-stable crystalline phases of zinc antimonide have been discovered.

引用

页码：1693 / 1696

页数：4

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