Low-Cost High-Performance Zinc Antimonide Thin Films for Thermoelectric Applications

被引:60
|
作者
Sun, Ye [1 ,2 ]
Christensen, Mogens [1 ,2 ]
Johnsen, Simon [1 ,2 ]
Nong, Ngo V. [3 ]
Ma, Yi [4 ]
Sillassen, Michael [2 ,5 ]
Zhang, Eryun [2 ,5 ]
Palmqvist, Anders E. C. [4 ]
Bottiger, Jorgen [2 ,5 ]
Iversen, Bo B. [1 ,2 ]
机构
[1] Aarhus Univ, Dept Chem, Ctr Mat Crystallog, DK-8000 Aarhus C, Denmark
[2] Aarhus Univ, INANO, DK-8000 Aarhus C, Denmark
[3] Tech Univ Denmark, Riso Natl Lab Sustainable Energy, Fuel Cells & Solid State Chem Div, DK-4000 Roskilde, Denmark
[4] Chalmers Univ Technol, Dept Chem & Biol Engn, SE-41296 Gothenburg, Sweden
[5] Aarhus Univ, Dept Phys, DK-8000 Aarhus C, Denmark
基金
新加坡国家研究基金会;
关键词
thermoelectrics; thin films; magnetron sputtering; zinc antimonide; thermal stability; PHONON-GLASS; ZN4SB3;
D O I
10.1002/adma.201104947
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Zinc antimonide thin films with high thermoelectric performance are produced by a simple sputtering method. The phase-pure Zn4Sb3 and ZnSb thin films fulfill the key requirements for commercial TE power generation: cheap elements, cheap fabrication method, high performance and thermal stability. In addition, two completely new meta-stable crystalline phases of zinc antimonide have been discovered.
引用
收藏
页码:1693 / 1696
页数:4
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