35Cl NQR spectra, structure, and mutual influence of substituents in the series of chlorine-containing organic compounds of pentavalent phosphorus

被引：1

作者：

Semin, GK ^{[1
]}

Tsvetkov, EN ^{[1
]}

Khotsyanova, TL ^{[1
]}

Bryukhova, EV ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 117813, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 1999年 / 48卷 / 05期

关键词：

Cl-35 NQR spectra; field constant of NQR frequency; chlorine-containing organic compounds of pentavalent phosphorus;

D O I：

10.1007/BF02494635

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Regularities of transmission of the effect of equatorial and axial substituents were established for a number of chlorine-containing organic compounds of pentavalent phosphorus using Cl-35 NQR spectra. The field constants of Cl-35 NQR frequencies of the chlorine atoms participating in the P-Cl bond were estimated for a series of tetrahedral phosphorus ions. The Cl-35 NQR frequencies of chlorine atoms in tetracoordinated ions of pentavalent phosphorus and in analogous isoelectronic silicon compounds are related by a linear dependence.

引用

页码：906 / 913

页数：8

共 49 条

[41] Features of the molecular structure of compounds of (Cl3PNAr)2 series (Ar = C6H4Z, Z = H, Cl) by quantum-chemical calculations and the data of 35Cl nuclear quadrupole resonance
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[42] Quantum-chemical calculations of NMR chemical shifts of organic molecules: XIV. Solvation effects in calculations of chemical shifts in 13C NMR spectra of chlorine-containing compounds
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[43] Features of the Molecular Structure of Compounds of (Cl3PNAr)2 Series (Ar = C6H4Z, Z = H, Cl) by Quantum-Chemical Calculations and the Data of 35Cl Nuclear Quadrupole Resonance
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[44] Quantum-chemical calculations of NMR chemical shifts of organic molecules: XIV. Solvation effects in calculations of chemical shifts in 13C NMR spectra of chlorine-containing compounds
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[45] Quantum-chemical study of chlorophosphoranes: III. Structure of the molecules of the series (X,X') a P(Cl3) e . Mutual influence of axial and equatorial substituents
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[46] Quantum-chemical study of chlorophosphoranes: II. Structure of molecules of (Cl2) a P(Cl n X3-n ) e series, and mutual influence of axial and equatorial substituents
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[47] Quantum-chemical study of chlorophosphoranes: III. Structure of the molecules of the series (X,X′)aP(Cl3)e. Mutual influence of axial and equatorial substituents
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Russian Journal of General Chemistry, 2009, 79 : 2126 - 2130
[48] INDUCTION STUDIES IN SEVERAL GROUPS OF HALOGEN-CONTAINING ORGANIC COMPOUNDS BY THEIR CL-35, BR-79, OR BR-81 PURE QUADRUPOLE RESONANCE SPECTRA
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BRAY, PJ
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[49] Quantum-chemical study of chlorophosphoranes: II. Structure of molecules of (Cl2)aP(ClnX3−n)e series, and mutual influence of axial and equatorial substituents
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