35Cl NQR spectra, structure, and mutual influence of substituents in the series of chlorine-containing organic compounds of pentavalent phosphorus

被引：1

作者：

Semin, GK ^{[1
]}

Tsvetkov, EN ^{[1
]}

Khotsyanova, TL ^{[1
]}

Bryukhova, EV ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 117813, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 1999年 / 48卷 / 05期

关键词：

Cl-35 NQR spectra; field constant of NQR frequency; chlorine-containing organic compounds of pentavalent phosphorus;

D O I：

10.1007/BF02494635

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Regularities of transmission of the effect of equatorial and axial substituents were established for a number of chlorine-containing organic compounds of pentavalent phosphorus using Cl-35 NQR spectra. The field constants of Cl-35 NQR frequencies of the chlorine atoms participating in the P-Cl bond were estimated for a series of tetrahedral phosphorus ions. The Cl-35 NQR frequencies of chlorine atoms in tetracoordinated ions of pentavalent phosphorus and in analogous isoelectronic silicon compounds are related by a linear dependence.

引用

页码：906 / 913

页数：8

共 49 条

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Journal of Molecular Structure, 345
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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (17) : 4227 - 4230
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Widdifield, Cory M.
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MAGNETIC RESONANCE IN CHEMISTRY, 2024, 62 (03) : 156 - 168
[37] -35CL NUCLEAR-QUADRUPOLE RESONANCE SPECTRA IN STUDYING STRUCTURE OF PHOSPHAZOPHOSPHONYLS AS REACTION-PRODUCTS OF AMIDO ESTERS OF ALKYLPHOSPHONIC ACIDS WITH PHOSPHORUS PENTACHLORIDE
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KYUNTSEL, IA
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ZHURNAL OBSHCHEI KHIMII, 1973, 43 (01): : 9 - 12
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KOORDINATSIONNAYA KHIMIYA, 1996, 22 (01): : 33 - 37
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WHITEHEA.HC
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ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1974, : 122 - 122

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