Solid state synthesis and crystal structure of K3SI

被引：0

作者：

Zhao, ZQ

Liu, X

Chen, WT

Li, Y

Wu, AQ

Zeng, HY

Guo, GC ^{[1
]}

Huang, JS

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2006年 / 25卷 / 02期

关键词：

crystal structure; solid state synthesis; ternary alkali metal chalcogenide halide;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new ternary alkali metal chalcogenide halide, K3SI, has been synthesized by solid state reaction method and structurally characterized by X-ray crystallography. The crystal belongs to hexagonal, space group P6(3)cm with a = 1 1.699(1), c = 5.8279(9) angstrom, M-r = 276.26, V = 690.8(1) angstrom(3), Z = 6, D-c = 3.985 g/cm(3), F(000) = 756, mu = 9.913 mm(-1), S = 1.004, R = 0.0719 and wR = 0.2204. The title compound is the first example containing S anion in the ternary alkali metal chalcogenide halides family M(3)QX (M = alkali metal, Q = chalcogenide, X = halide), which crystallizes in the hexagonal anti-perovskite structure type.

引用

页码：159 / 162

页数：4

共 50 条

[41] STUDIES ON SOLID STATE REACTIONS OF COORDINATION COMPOUNDS XXXXV. SOLID STATE SYNTHESIS AND CRYSTAL STRUCTURE OF [MoAg3BrS4I3][（n-Bu）4N]3
Cai Jin-Hua Weng Lin-Hong Kang Bei-ShengFujian Institute of Research on the Structure of Matter
结构化学, 1993, (01) : 22 - 25
[42] Synthesis, crystal structure and thermal decomposition of solid complex
Jia, RR
Yang, YX
Chen, YR
Jia, YQ
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2004, 76 (01) : 157 - 163
[43] K2AG4SE3, SYNTHESIS AND CRYSTAL-STRUCTURE
BRONGER, W
SCHILS, H
JOURNAL OF THE LESS-COMMON METALS, 1982, 83 (02): : 287 - 291
[44] Synthesis and crystal structure of K3[NpO4(OH)2]
Krot N.N.
Grigor'Ev M.S.
Charushnikova I.A.
Radiochemistry, 2014, 56 (05) : 476 - 480
[45] Synthesis and crystal structure of topiramate azidosulfate at 90 K and 298 K
Priyanka, Prabhakar
Jayanna, Bidarur K.
Kumar, Haruvegowda Kiran
Vinaya
Divakara, Thayamma R.
Yathirajan, Hemmige S.
Glidewell, Christopher
Parkin, Sean
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2022, 78 : 984 - +
[46] Solid Synthesis and Crystal Structure of Compound[ （PPh3 ）3,Cu2MoOS3]
Lin Zhen-Guang(Department of Chemistry
Chen Hua-Yang
Chi Li-Sheng(State Key Laboratory of Structural Chemistry
结构化学, 1996, (04) : 33+334 - 336
[47] The binary silicides Eu5Si3 and Yb3Si5 -: Synthesis, crystal structure, and chemical bonding
Pottgen, R
Hoffmann, RD
Kussmann, D
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1998, 624 (06): : 945 - 951
[48] Unraveling the Crystal Structure of Sodium Tetrabenzylborate: Synthesis through the Sodium Borohydride Reduction of Benzaldehyde in the Solid State
Castilla-Martinez, Carlos A.
Granier, Dominique
Yot, Pascal G.
Demirci, Umit B.
INORGANICS, 2024, 12 (07)
[49] Study on facile synthesis, crystal structure, and solid-state fluorescence of dicyclohexane-annelated anthracene
Kitamura, Chitoshi
Matsumoto, Chika
Kawatsuki, Nobuhiro
Yoneda, Akio
Asada, Kohei
Kobayashi, Takashi
Naito, Hiroyoshi
Bulletin of the Chemical Society of Japan, 2008, 81 (06): : 754 - 756
[50] Solid state synthesis of novel charge transfer complex and studies of its crystal structure and optical properties
Neupane, Umesh
Rai, R. N.
JOURNAL OF SOLID STATE CHEMISTRY, 2018, 268 : 67 - 74

← 1 2 3 4 5 →