Solid state synthesis and crystal structure of K3SI

被引：0
|
作者：
Zhao, ZQ
Liu, X
Chen, WT
Li, Y
Wu, AQ
Zeng, HY
Guo, GC [1 ]
Huang, JS
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2006年 / 25卷 / 02期
关键词：
crystal structure; solid state synthesis; ternary alkali metal chalcogenide halide;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new ternary alkali metal chalcogenide halide, K3SI, has been synthesized by solid state reaction method and structurally characterized by X-ray crystallography. The crystal belongs to hexagonal, space group P6(3)cm with a = 1 1.699(1), c = 5.8279(9) angstrom, M-r = 276.26, V = 690.8(1) angstrom(3), Z = 6, D-c = 3.985 g/cm(3), F(000) = 756, mu = 9.913 mm(-1), S = 1.004, R = 0.0719 and wR = 0.2204. The title compound is the first example containing S anion in the ternary alkali metal chalcogenide halides family M(3)QX (M = alkali metal, Q = chalcogenide, X = halide), which crystallizes in the hexagonal anti-perovskite structure type.
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页码：159 / 162
页数：4
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