Hypervalent Bromine Compounds: Smaller, More Reactive Analogues of Hypervalent Iodine Compounds

被引：32

作者：

Farooq, Umar ^{[1
]}

Shah, Azhar-ul-Haq Ali ^{[1
]}

Wirth, Thomas ^{[1
]}

机构：

[1] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, S Glam, Wales

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 06期

关键词：

alkyne coupling; hypervalent bromine compounds; hypervalent iodine compounds; Michael addition; oxidation; ONIUM IONS; CHEMISTRY; 1-ALKYNYL(ARYL)(TETRAFLUOROBORATO)-LAMBDA(3)-BROMANES; TRIFLUORIDE; DIRECTIONS; YLIDES;

D O I：

10.1002/anie.200805027

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Moving up a row in the Periodic Table leads from hypervalent iodine compounds to hypervalent bromine compounds, which are now readily available (see scheme). These compounds are more reactive than the well-known heavier analogues and undergo new reactions. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1018 / 1020

页数：3

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