Synthesis of novel N-heterocyclic carbene-Rh complexes derived from L-proline and their catalysis in the addition of arylboronic acids to aldehydes

被引：17
|
作者：
Zhang, WF [1 ]
Qin, YC [1 ]
Zhang, SJ [1 ]
Luo, MM [1 ]
机构：
[1] Sichuan Univ, Coll Chem, Key Lab Green Chem & Technol, Minist Educ, Chengdu 610064, Peoples R China
来源：
ARKIVOC | 2005年
关键词：
N-heterocyclic carbene; L-proline; chiral; arylboronic acid; aldehyde;
D O I：
10.3998/ark.5550190.0006.e05
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Novel chiral imidazolium salts and a stable N-heterocyclic carbene-Rh complex derived from L-proline have been synthesized. The N-heterocyclic carbene-Rh complexes either generated in situ or pre-synthesized are active catalysts for the addition reaction of arylboronic acids to aldehydes affording the corresponding secondary alcohols in excellent yields.
引用
收藏
页码：39 / 48
页数：10
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