Liquid fuel production by aqueous phase catalytic transformation of biomass for aviation

被引:24
|
作者
Wang, Tiejun [1 ]
Qiu, Songbai [1 ]
Weng, Yujing [1 ]
Chen, Lungang [1 ]
Liu, Qiying [1 ]
Long, Jinxing [1 ]
Tan, Jin [1 ]
Zhang, Qing [1 ]
Zhang, Qi [1 ]
Ma, Longlong [1 ]
机构
[1] Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China
基金
中国国家自然科学基金;
关键词
Liquid fuels; Aqueous phase; Catalytic transformation; Biomass; Aviation; FAST PYROLYSIS; CONVERSION; SORBITOL; ALKANES; REACTOR;
D O I
10.1016/j.apenergy.2015.08.116
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The commercial jet fuels usually contain about 40% aromatics and naphthene. However, conventional technologies on bio-jet fuels production by hydrodeoxygenation of plant oil and biomass gasification/Fischer-Tropsch synthesis can't produce renewable aromatics. In this paper, the liquid fuels with high aromatics content were produced by aqueous phase catalytic conversion of biomass sugar/polyol over Ni@HZSM-5/MCM-41 catalysts. Liquid fuel yield of 32 wt% with aromatics content of 84.3% was obtained under the conditions of 300 degrees C, WHSV of 1.25 h(-1), GHSV of 2500 h(-1) and 4.0 MPa of hydrogen pressure with mixed polyol (60% sorbitol + 40% xylitol) as feedstocks. The produced bio-aromatics are substituted benzenes, naphthalenes, and aromatic olefins, which is a wonderful crude oil to be used as jet fuels after it was hydrogenated to improve quality (deep deoxygenation/chemical bond saturation). (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:329 / 335
页数:7
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