Liquid fuel production by aqueous phase catalytic transformation of biomass for aviation

被引：24

作者：

Wang, Tiejun ^{[1
]}

Qiu, Songbai ^{[1
]}

Weng, Yujing ^{[1
]}

Chen, Lungang ^{[1
]}

Liu, Qiying ^{[1
]}

Long, Jinxing ^{[1
]}

Tan, Jin ^{[1
]}

Zhang, Qing ^{[1
]}

Zhang, Qi ^{[1
]}

Ma, Longlong ^{[1
]}

机构：

[1] Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China

来源：

APPLIED ENERGY | 2015年 / 160卷

基金：

中国国家自然科学基金;

关键词：

Liquid fuels; Aqueous phase; Catalytic transformation; Biomass; Aviation; FAST PYROLYSIS; CONVERSION; SORBITOL; ALKANES; REACTOR;

D O I：

10.1016/j.apenergy.2015.08.116

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

The commercial jet fuels usually contain about 40% aromatics and naphthene. However, conventional technologies on bio-jet fuels production by hydrodeoxygenation of plant oil and biomass gasification/Fischer-Tropsch synthesis can't produce renewable aromatics. In this paper, the liquid fuels with high aromatics content were produced by aqueous phase catalytic conversion of biomass sugar/polyol over Ni@HZSM-5/MCM-41 catalysts. Liquid fuel yield of 32 wt% with aromatics content of 84.3% was obtained under the conditions of 300 degrees C, WHSV of 1.25 h(-1), GHSV of 2500 h(-1) and 4.0 MPa of hydrogen pressure with mixed polyol (60% sorbitol + 40% xylitol) as feedstocks. The produced bio-aromatics are substituted benzenes, naphthalenes, and aromatic olefins, which is a wonderful crude oil to be used as jet fuels after it was hydrogenated to improve quality (deep deoxygenation/chemical bond saturation). (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：329 / 335

页数：7

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