A study of nitrobenzene hydrogenation over palladium/carbon catalysts

被引：80
|
作者：
Gelder, EA
Jackson, SD [1 ]
Lok, CM
机构：
[1] Univ Glasgow, Dept Chem, Glasgow G12 8QQ, Lanark, Scotland
[2] Synetix, Billingham TS23 1LB, Cleveland, England
来源：
CATALYSIS LETTERS | 2002年 / 84卷 / 3-4期
基金：
英国工程与自然科学研究理事会;
关键词：
palladium; nitrobenzene; hydrogenation; carbon; aniline; particle size effect;
D O I：
10.1023/A:1021432104496
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The hydrogenation of nitrobenzene has been studied over three palladium/carbon catalysts using methanol and isopropanol as solvents. A solvent and palladium particle size effect have both been observed, with the nature of the particle size effect dependent upon the solvent. This may be related to a change in the rate-determining step.
引用
收藏
页码：205 / 208
页数：4
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