A study of nitrobenzene hydrogenation over palladium/carbon catalysts

被引：80
|
作者：
Gelder, EA
Jackson, SD [1 ]
Lok, CM
机构：
[1] Univ Glasgow, Dept Chem, Glasgow G12 8QQ, Lanark, Scotland
[2] Synetix, Billingham TS23 1LB, Cleveland, England
来源：
CATALYSIS LETTERS | 2002年 / 84卷 / 3-4期
基金：
英国工程与自然科学研究理事会;
关键词：
palladium; nitrobenzene; hydrogenation; carbon; aniline; particle size effect;
D O I：
10.1023/A:1021432104496
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The hydrogenation of nitrobenzene has been studied over three palladium/carbon catalysts using methanol and isopropanol as solvents. A solvent and palladium particle size effect have both been observed, with the nature of the particle size effect dependent upon the solvent. This may be related to a change in the rate-determining step.
引用
收藏
页码：205 / 208
页数：4
相关论文
共 50 条
  • [31] SELECTIVE HYDROGENATION OF CARBON-MONOXIDE ON PALLADIUM CATALYSTS
    KIKUZONO, Y
    KAGAMI, S
    NAITO, S
    ONISHI, T
    TAMARU, K
    FARADAY DISCUSSIONS, 1981, 72 : 135 - 143
  • [32] RUTHENIUM-PALLADIUM CATALYSTS ON CARBON IN HYDROGENATION OF DIMETHYLETHYNYLCARBINOL
    SOKOLSKII, DV
    DZHARDAMALIEVA, KK
    DUKHOVNAYA, TM
    DINASYLOVA, SD
    ZHURNAL FIZICHESKOI KHIMII, 1977, 51 (05): : 1115 - 1117
  • [33] Hydrogenation of chlorate ions by commercial carbon supported palladium catalysts—a comparative study
    Emőke Sikora
    Gábor Karacs
    István Kocserha
    Gábor Muránszky
    Béla Fiser
    Béla Viskolcz
    László Vanyorek
    Reaction Kinetics, Mechanisms and Catalysis, 2020, 131 : 129 - 137
  • [34] Enhanced hydrogenation activity for palladium catalysts supported on carbon
    Shakya, Deependra
    Farzandh, Sharfa
    Banerjee, Ritubarna
    Regalbuto, John
    Chen, Donna
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 257
  • [35] Hydrogenation of nitrobenzene with supported transition metal catalysts in supercritical carbon dioxide
    Zhao, F
    Zhang, R
    Chatterjee, M
    Ikushima, Y
    Arai, M
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 227 : U1070 - U1070
  • [36] Selective hydrogenation of naphthols to tetralones over supported palladium catalysts in supercritical carbon dioxide solvent
    Mine, Eiichi
    Hiyoshi, Norihito
    Sato, Osamu
    Rode, Chandrashekhar V.
    Shirai, Masayuki
    CHEMISTRY LETTERS, 2006, 35 (07) : 780 - 781
  • [37] Effects of palladium particle size in hydrogenation of carbon dioxide to methanol over Pd/ZnO catalysts
    Lee, D
    Lee, JY
    Lee, JS
    CARBON DIOXIDE UTILIZATION FOR GLOBAL SUSTAINABILITY, 2004, 153 : 169 - 172
  • [38] HYDROGENATION OF PHENOL TO CYCLOHEXANONE OVER PALLADIUM AND ALKALI-DOPED PALLADIUM CATALYSTS
    NERI, G
    VISCO, AM
    DONATO, A
    MILONE, C
    MALENTACCHI, M
    GUBITOSA, G
    APPLIED CATALYSIS A-GENERAL, 1994, 110 (01) : 49 - 59
  • [39] Hydrogenation of nitrobenzene over a composite catalyst based on zeolite supported N-doped carbon nanotubes decorated with palladium
    Prekob, Adam
    Muranszky, Gabor
    Hutkai, Zsuzsa G.
    Pekker, Peter
    Kristaly, Ferenc
    Fiser, Bela
    Viskolcz, Bela
    Vanyorek, Laszlo
    REACTION KINETICS MECHANISMS AND CATALYSIS, 2018, 125 (02) : 583 - 593
  • [40] Heterogeneous Palladium Catalysts in the Hydrogenation of the Carbon-carbon Double Bond
    Grabovskii, Stanislav A.
    Akchurin, Timur, I
    Dokichev, Vladimir A.
    CURRENT ORGANIC CHEMISTRY, 2021, 25 (02) : 315 - 329
12345