First Tribo-Excited Chemical Reaction of a Stacked Lanthanide Coordination Polymer with an in Situ Reaction Monitor

被引：11
|
作者：
Kitagawa, Yuichi [1 ,2 ]
Naito, Ayu [3 ]
Fushimi, Koji [1 ]
Hasegawa, Yasuchika [1 ,2 ]
机构：
[1] Hokkaido Univ, Fac Engn, Kita Ku, Kita 13 Nishi 8, Sapporo, Hokkaido 0608628, Japan
[2] Hokkaido Univ, Inst Chem React Design & Discovery WPI ICReDD, Kita Ku, Kita 21 Nishi 10, Sapporo, Hokkaido 0010021, Japan
[3] Hokkaido Univ, Grad Sch Chem Sci & Engn, Kita Ku, Kita 13 Nishi 8, Sapporo, Hokkaido 0608628, Japan
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2021年 / 27卷 / 07期
关键词：
energy transfer; luminescence; photophysics; UV; Vis spectroscopy; TRIBOLUMINESCENCE; PHOTOCHEMISTRY; PHOTOOXIDATION; ANTHRACENE;
D O I：
10.1002/chem.202004485
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A tribo-excited chemical reaction using a stacked lanthanide coordination polymer is demonstrated for the first time. The polymer is composed of a Eu-III ion, hexafluoroacetylacetonato ligands, and an anthracene-based phosphine oxide bridge. The tightly stacked structure with hydrogen bonding was characterized by X-ray crystal structure analysis. The mechanical stimulus leads to tribo-excited oxidation in the Eu-III coordination polymer. Electron ionization mass spectroscopy and photo-spectroscopic analysis reveal that the chemical product afforded by tribo-oxidation is different from that obtained by photo-oxidation.
引用
收藏
页码：2279 / 2283
页数：5
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