Construction and photoluminescence properties of two novel zinc(II) and cadmium(II) benzyl-tetrazole coordination polymers

被引：41

作者：

Liu, Biao ^{[1
]}

Qiu, Yong-Cai ^{[1
]}

Peng, Guo ^{[1
]}

Ma, Li ^{[1
]}

Jin, Li-Ming ^{[1
]}

Cai, Jin-Biao ^{[1
]}

Deng, Hong ^{[1
]}

机构：

[1] S China Normal Univ, Power Generat Guangdong Univ, Key Lab Electrochem Technol Energy Storage, Sch Chem & Environm, Guangzhou 510006, Guangdong, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2009年 / 12卷 / 12期

基金：

中国国家自然科学基金;

关键词：

Tetrazole; Helical chain; Fluorescence; Lifetime; LIGAND SYNTHESIS; 5-SUBSTITUTED; 1H-TETRAZOLES; SUPRAMOLECULAR ARCHITECTURES; COPPER(II); WATER; DIFFRACTION; FRAMEWORK; NITRILES; BROMIDE; EPR;

D O I：

10.1016/j.inoche.2009.09.018

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new d(10) coordination polymers. Zn(Beta)(2) (1) and Cd-2(Beta)(3)Cl(H2O) (2) (Hbeta = 5-benzyl-tetrazole) have been synthesized by the in situ [3 + 2] cycloaddition reaction of 5-benzylacetonitrile, sodium azide and MCl2 [M = Zn (1); M = Cd (2)] under hydrothermal condition, Complex 1 is a coordination polymer comprised of numerous mildly undulated two-dimensional (2D) layers with a (4,4) topological network; while complex 2 is a 3D coordination framework constructed from the interconnection of various helical chains through cadmium-chlorine bridges. Furthermore, the luminescence properties of two complexes have been investigated. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：1200 / 1203

页数：4

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