Synthesis, structure and optical properties of novel double penetration polypseudorotaxane compound templated by branched divalent cation template

被引：1

作者：

Wang, Fu-Rong ^{[1
]}

Li, Su-Min ^{[1
]}

Niu, Yun-Yin ^{[1
]}

Hou, Hong-Wei ^{[1
]}

机构：

[1] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Henan, Peoples R China

来源：

JOURNAL OF THE IRANIAN CHEMICAL SOCIETY | 2019年 / 16卷 / 05期

基金：

美国国家科学基金会;

关键词：

1; 3-Bis(4-cyanopyridine) propane bromine salt; Double penetration polymer; Inorganic-organic hybrid; Photocatalysis; METAL; POLYMERS;

D O I：

10.1007/s13738-018-1568-8

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This study is directed to branched cationic template, 1,3-bis(4-cyanopyridine) propane bromine salt (Bcpyp2Br), which connected by metal pseudohalides to form novel double penetration polymeric compound: {(Bcpyp)[Cu-2(SCN)(3.33)Br-0.68]0.68H(2)O} (1). The structure was determined by single crystal X-ray diffraction analysis and further characterized by infrared spectra (IR), elemental analysis, powder X-ray diffraction (PXRD), and thermogravimetric (TG) analysis. Compound 1 also shows the better photocatalysis ability of degrading methylene blue (MB) than degrading rhodamine(RhB) and methyl orange(MO) in water under 500W Xe vapor lamp irradiation.

引用

页码：939 / 944

页数：6

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