Synthesis, structure and optical properties of novel double penetration polypseudorotaxane compound templated by branched divalent cation template

被引：1
|
作者：
Wang, Fu-Rong [1 ]
Li, Su-Min [1 ]
Niu, Yun-Yin [1 ]
Hou, Hong-Wei [1 ]
机构：
[1] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Henan, Peoples R China
来源：
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY | 2019年 / 16卷 / 05期
基金：
美国国家科学基金会;
关键词：
1; 3-Bis(4-cyanopyridine) propane bromine salt; Double penetration polymer; Inorganic-organic hybrid; Photocatalysis; METAL; POLYMERS;
D O I：
10.1007/s13738-018-1568-8
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This study is directed to branched cationic template, 1,3-bis(4-cyanopyridine) propane bromine salt (Bcpyp2Br), which connected by metal pseudohalides to form novel double penetration polymeric compound: {(Bcpyp)[Cu-2(SCN)(3.33)Br-0.68]0.68H(2)O} (1). The structure was determined by single crystal X-ray diffraction analysis and further characterized by infrared spectra (IR), elemental analysis, powder X-ray diffraction (PXRD), and thermogravimetric (TG) analysis. Compound 1 also shows the better photocatalysis ability of degrading methylene blue (MB) than degrading rhodamine(RhB) and methyl orange(MO) in water under 500W Xe vapor lamp irradiation.
引用
收藏
页码：939 / 944
页数：6
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