Pd-catalyzed chemoselective threefold cross-coupling of triarylbismuths with benzylic bromides

被引：15

作者：

Rao, Maddali L. N. ^{[1
]}

Dhanorkar, Ritesh J. ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India

来源：

RSC ADVANCES | 2013年 / 3卷 / 19期

关键词：

ORGANIC ELECTROPHILES; MANGANESE HALIDES; ZINC REAGENTS; ARYL HALIDES; DIARYLMETHANES; DERIVATIVES; PHOSPHATES; HETEROARYL; CHLORIDES; CARBON;

D O I：

10.1039/c3ra40413g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient palladium-catalyzed protocol was demonstrated for the chemoselective cross-coupling of functionalized benzylic bromides with triarylbismuth reagents. Under the established conditions, catalyzed by palladium in the presence of K3PO4 base in DMA at 90 degrees C for 1 h, the threefold arylations using triarylbismuth reagents proceeded smoothly with electronically diverse benzylic bromides. All the coupling reactions furnished the corresponding functionalized diarylmethanes in high yields.

引用

页码：6794 / 6798

页数：5

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