One-pot reductive amination of carbonyl compounds with nitro compounds over a Ni/NiO composite

被引:13
|
作者
Kita, Yusuke [1 ]
Kai, Sayaka [1 ]
Rustad, Lesandre Binti Supriadi [1 ]
Kamata, Keigo [1 ]
Hara, Michikazu [1 ,2 ]
机构
[1] Tokyo Inst Technol, Inst Innovat Res, Lab Mat & Struct, Midori Ku, Nagatsuta Cho 4259, Yokohama, Kanagawa 2268503, Japan
[2] Japan Sci & Technol Agcy JST, Adv Low Carbon Technol Res & Dev Program ALCA, 4-1-8 Honcho, Kawaguchi, Saitama 3320012, Japan
基金
日本科学技术振兴机构;
关键词
CO-N-X; SECONDARY-AMINES; HYDROGEN DONOR; NANOPARTICLES; CATALYSTS; NITROARENES; METAL; ALDEHYDES; LIGANDS; NIO;
D O I
10.1039/d0ra06937j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Easily prepared Ni/NiO acts as a heterogeneous catalyst for the one-pot reductive amination of carbonyl compounds with nitroarenes to afford secondary amines with H(2)as a hydride source. This catalytic system does not require a special technique to avoid air-exposure, in contrast to the common heterogeneous Ni catalysts.
引用
收藏
页码:32296 / 32300
页数:5
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