One-pot reductive amination of carbonyl compounds with nitro compounds over a Ni/NiO composite

被引：13

作者：

Kita, Yusuke ^{[1
]}

Kai, Sayaka ^{[1
]}

Rustad, Lesandre Binti Supriadi ^{[1
]}

Kamata, Keigo ^{[1
]}

Hara, Michikazu ^{[1
,2
]}

机构：

[1] Tokyo Inst Technol, Inst Innovat Res, Lab Mat & Struct, Midori Ku, Nagatsuta Cho 4259, Yokohama, Kanagawa 2268503, Japan

[2] Japan Sci & Technol Agcy JST, Adv Low Carbon Technol Res & Dev Program ALCA, 4-1-8 Honcho, Kawaguchi, Saitama 3320012, Japan

来源：

RSC ADVANCES | 2020年 / 10卷 / 54期

基金：

日本科学技术振兴机构;

关键词：

CO-N-X; SECONDARY-AMINES; HYDROGEN DONOR; NANOPARTICLES; CATALYSTS; NITROARENES; METAL; ALDEHYDES; LIGANDS; NIO;

D O I：

10.1039/d0ra06937j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Easily prepared Ni/NiO acts as a heterogeneous catalyst for the one-pot reductive amination of carbonyl compounds with nitroarenes to afford secondary amines with H(2)as a hydride source. This catalytic system does not require a special technique to avoid air-exposure, in contrast to the common heterogeneous Ni catalysts.

引用

页码：32296 / 32300

页数：5

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