Facile synthesis of 1,1-disubstituted taurines

被引：43
|
作者：
Huang, JX [1 ]
Du, DM [1 ]
Xu, JX [1 ]
机构：
[1] Peking Univ, Coll Chem & Mol Engn, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Beijing 100871, Peoples R China
来源：
SYNTHESIS-STUTTGART | 2006年 / 02期
关键词：
amino acid; aminoalkanesulfonic acid; epoxide; episulfide; ketone; synthesis; taurine;
D O I：
10.1055/s-2005-924767
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A series of 1,1-disubstituted taurines was synthesized expeditiously from ketones via the Corey-Chaykovsky epoxidation with dimethylsulfonium methylide, episulfidation with potassium sulfocyanate, ring-opening reaction with ammonia in the presence of,silver nitrate, followed by treatment with hydrogen Sulfide and oxidation with performic acid.
引用
收藏
页码：315 / 319
页数：5
相关论文
共 50 条
  • [31] TRIALKYLALLENES FROM 1,1-DISUBSTITUTED PROPARGYLIC ACETATES
    DELBECQ, F
    GORE, J
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1976, 15 (08): : 496 - 497
  • [32] QUANTUM CHEMICAL DATA 1,1-DISUBSTITUTED ETHYLENES
    HERR, ML
    COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1972, 37 (10) : 3219 - &
  • [33] Synthesis of α-tertiary allylsilanes by palladium-catalyzed hydrosilylation of 1,1-disubstituted allenes
    Li, Kaidi
    Nie, Ming
    Tang, Wenjun
    GREEN SYNTHESIS AND CATALYSIS, 2020, 1 (02): : 171 - 174
  • [34] Hydroformylation of ω-functionalized 1,1-disubstituted alkenes and its use toward the synthesis of (±)muscone
    Takahashi, T
    Machida, K
    Kido, Y
    Nagashima, K
    Ebata, S
    Doi, T
    CHEMISTRY LETTERS, 1997, (12) : 1291 - 1292
  • [35] SYNTHESIS OF 1,1-DISUBSTITUTED ETHENES BY MEANS OF SEQUENTIAL CROSS-COUPLING REACTIONS
    FIANDANESE, V
    MARCHESE, G
    NASO, F
    RONZINI, L
    SYNTHESIS-STUTTGART, 1987, (11): : 1034 - 1036
  • [36] Synthesis of 1,1-disubstituted tetrahydro-β-carbolines from 2-methyleneaziridines
    Mumford, Peter M.
    Shiers, Jason J.
    Tarver, Gary J.
    Hayes, Jerome F.
    Shipman, Michael
    TETRAHEDRON LETTERS, 2008, 49 (21) : 3489 - 3491
  • [37] exo-Glycals: Intermediates in the Synthesis of 1,1-Disubstituted C-Glycosides
    Woodward, Hannah
    Smith, Nichola
    Gallagher, Timothy
    SYNLETT, 2010, (06) : 869 - 872
  • [38] A Titanium(III)-Catalyzed Reductive Umpolung Reaction for the Synthesis of 1,1-Disubstituted Tetrahydroisoquinolines
    Hieu-Trinh Luu
    Wiesler, Stefan
    Frey, Georg
    Streuff, Jan
    ORGANIC LETTERS, 2015, 17 (10) : 2478 - 2481
  • [39] Intermolecular alkyne hydroaminations involving 1,1-disubstituted hydrazines
    Cao, CS
    Shi, YH
    Odom, AL
    ORGANIC LETTERS, 2002, 4 (17) : 2853 - 2856
  • [40] OXIDATION OF 1,1-DISUBSTITUTED HYDRAZINES TO TETRAZENES WITH BENZENESELENINIC ACID
    BACK, TG
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (11) : 530 - 531
12345