Intermolecular Cross-coupling Between η2-Olefin and η1-Allyl Ligands in Cationic Platinum(II) and Palladium(II) Complexes

被引：12

作者：

Cucciolito, Maria E. ^{[1
]}

Vitagliano, Aldo ^{[1
]}

机构：

[1] Univ Naples Federico II, Dipartimento Chim Paolo Corradini, I-80126 Naples, Italy

来源：

ORGANOMETALLICS | 2008年 / 27卷 / 23期

关键词：

D O I：

10.1021/om8006882

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The terminal (gamma) carbon atom of the allyl system in eta(1)-allyl platinum and palladium complexes of the tridentate pincer ligand PNP (PNP = 2,6-bis-diphenylphosphinomethylpyridine) attacks the coordinated olefin of dicationic platinum and palladium complexes with the same ligand, producing binuclear species in which the metal formerly pi-coordinated becomes sigma-bonded, and the metal formerly sigma-bonded becomes pi-coordinated. The reaction can be run catalytically with respect to the addition of ethylene to a eta(1)-allyl complex, using the dicationic ethylene complex as catalyst.

引用

页码：6360 / 6363

页数：4

共 50 条

[41] Thermal decomposition of nickel(II), palladium(II), and platinum(II) complexes of N-allyl-N′-pyrimidin-2ylthiourea
Saud M. A. Katib
Journal of Thermal Analysis and Calorimetry, 2011, 103 : 647 - 652
[42] Palladium(II) and platinum(II) complexes with N1-hydroxyethyl-3,5-pyrazole derived ligands
Perez, Jose A.
Montoya, Vanessa
Ayllon, Jose A.
Font-Bardia, Merce
Calvet, Teresa
Pons, Josefina
INORGANICA CHIMICA ACTA, 2013, 394 : 21 - 30
[43] Five-coordinate complexes of palladium(II) and platinum(II) with α-diimine and 1,5-cyclooctadiene ligands
Di Bianca, F
Bandoli, G
Dolmella, A
Antonaroli, S
Crociani, B
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (02): : 212 - 217
[44] MECHANISM OF NUCLEOPHILIC-ATTACK BY DIETHYLAMINE ON CATIONIC PALLADIUM(II) ALLYL COMPLEXES CONTAINING ALPHA-DIIMINE LIGANDS
CROCIANI, B
ANTONAROLI, S
DIBIANCA, F
CANOVESE, L
VISENTIN, F
UGUAGLIATI, P
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (07): : 1145 - 1151
[45] Investigating Arylazoformamide Ligands in Palladium(II) Precatalysts through the Suzuki-Miyaura Cross-Coupling Reaction
Tiwari, Laxmi
Hulley, Elliott B.
Waynant, Kristopher V.
JOURNAL OF ORGANIC CHEMISTRY, 2024, 89 (24): : 17917 - 17925
[46] Metal complexes of biologically important ligands, CXXV [1]. Palladium(II) and platinum(II) complexes of quinine derivatives and in vitro tests
Hubel, Roland
Jelinek, Tomas
Beck, Wolfgang
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 2000, 55 (09): : 821 - 833
[47] Metal complexes of biologically important ligands, CXXV [1]. Palladium(II) and platinum(II) complexes of quinine derivatives and in vitro tests
Hubel, R
Jelinek, T
Beck, W
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2000, 55 (09): : 821 - 833
[48] Functionalized nitrogen ligands (C-N) for palladium catalyzed cross-coupling reactions (part II)
Kumbhar, Arjun
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2019, 881 : 79 - 129
[49] Synthesis, Characterization, and Antimicrobial Activity of Palladium(II) and Platinum(II) Complexes with 2-Substituted Benzoxazole Ligands
Samota, Mahesh Kumar
Seth, Gita
HETEROATOM CHEMISTRY, 2010, 21 (01) : 44 - 50
[50] Synthesis, and characterization of palladium(II) and platinum(II) complexes with α-hydroxy[1-(2-ethoxyethyl) piperidin-4-yl]phosphonate and use of the palladium(II) complex as pre-catalyst in Suzuki-Miyaura cross-coupling reactions
Kystaubayeva, N. U.
Durap, Feyyaz
Zharkynbek, T. Y.
Yu, V. K.
Aydemir, Murat
Meric, Nermin
Zazybin, A. G.
Ten, A. Yu
Rafikova, Kh S.
Binbay, Nil E.
Celik, Omer
JOURNAL OF MOLECULAR STRUCTURE, 2022, 1270

← 1 2 3 4 5 →