Synthesis, and characterization of palladium(II) and platinum(II) complexes with α-hydroxy[1-(2-ethoxyethyl) piperidin-4-yl]phosphonate and use of the palladium(II) complex as pre-catalyst in Suzuki-Miyaura cross-coupling reactions

被引：3

作者：

Kystaubayeva, N. U. ^{[1
,2
]}

Durap, Feyyaz ^{[3
]}

Zharkynbek, T. Y. ^{[2
,4
]}

Yu, V. K. ^{[2
]}

Aydemir, Murat ^{[3
]}

Meric, Nermin ^{[3
]}

Zazybin, A. G. ^{[1
]}

Ten, A. Yu ^{[1
,2
]}

Rafikova, Kh S. ^{[1
]}

Binbay, Nil E. ^{[5
]}

Celik, Omer ^{[6
]}

机构：

[1] Kazakh British Tech Univ, Tole Bi Str 59, Alma Ata 050010, Kazakhstan

[2] Inst Chem Sci, Walikhanov Str 106, Alma Ata 050010, Kazakhstan

[3] Dicle Univ, Sci Fac, Dept Chem, TR-21280 Diyarbakir, Turkey

[4] Al Farabi Kazakh Natl Univ, Al Farabi Ave 71-23, Alma Ata 050040, Kazakhstan

[5] Dicle Univ, Vocat Sch, Dept Elect, TR-21280 Diyarbakir, Turkey

[6] Dicle Univ, Smart Lab, TR-21280 Diyarbakir, Turkey

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2022年 / 1270卷

关键词：

a-hydroxy[1-(2-ethoxyethyl)piperidin-4-yl]phosphonate; Pd(II) and Pt(II) complexes; Suzuki-Miyaura reaction; DFT calculations; TRANSFER HYDROGENATION; SPECTROSCOPIC CHARACTERIZATION; EFFICIENT CATALYST; NANOPARTICLES; DERIVATIVES; NANOCLUSTERS; LIGANDS; WATER; ACID;

D O I：

10.1016/j.molstruc.2022.133912

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Complexes [MCl2{(L1}2] ( M = Pd, Pt) were obtained by the reaction of the alpha-Hydroxy[1-(2-ethoxyethyl )piperidin-4-yl]phosphonate as ligand with [MCl2(COD)] ( M = Pd, Pt). The new compounds were characterized by NMR and IR spectroscopy, and microanalysis. In addition, representative solid-state structure of the ligand was determined using single crystal X-ray diffraction analysis. Furthermore, ab ini-tio quantum calculations of the ligand and its complexes were also carried out using density functional theory to better understand their chemical behaviors. Finally, the palladium(II) complex of the ligand was tested as a potential catalyst in the Suzuki-Miyaura cross-coupling reactions. (c) 2022 Elsevier B.V. All rights reserved.

引用

页数：9

共 50 条

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