Spontaneous symmetry breaking of Co(II) metal-organic frameworks from achiral precursors via asymmetrical crystallization

被引：17
|
作者：
Yu, Ya-Dong
Luo, Chan
Liu, Bao-Yu
Huang, Xiao-Chun [1 ]
Li, Dan
机构：
[1] Shantou Univ, Dept Chem, Guangzhou 515063, Guangdong, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 77期
关键词：
ABSOLUTE CHIRAL INDUCTION; COORDINATION POLYMER; SPONTANEOUS RESOLUTION; ENANTIOSELECTIVE SEPARATION; HOMOCHIRAL CRYSTALLIZATION; MICROPOROUS FRAMEWORK; POLARIZED-LIGHT; CATALYSIS; LIGAND; AMPLIFICATION;
D O I：
10.1039/c5cc06166k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The racemic conglomerate (1P-NH3 + 1M-NH3) and enantioenriched bulk samples (1P-H2O or 1M-NH3) of Co(II) metal-organic frameworks were obtained from achiral precursors under different solvothermal conditions. The bulk homochirality was generated through asymmetrical crystallization in the absence of any chiral additives confirmed by single crystal X-ray diffraction and CD spectroscopy.
引用
收藏
页码：14489 / 14492
页数：4
相关论文
共 50 条
  • [1] Spontaneous Resolution and Structure Transformation of NiII Metal-Organic Frameworks from an Achiral Precursor
    Tao, Ye
    Yang, Cheng
    Fang, Han
    Bian, He-Dong
    Xu, Xiao-ling
    Huang, Fu-Ping
    CRYSTAL GROWTH & DESIGN, 2019, 19 (06) : 3358 - 3364
  • [2] Symmetry-Breaking Charge Transfer in Metal-Organic Frameworks
    Rajasree, Sreehari Surendran
    Fry, H. Christopher
    Gosztola, David J.
    Saha, Bapan
    Krishnan, Riya
    Deria, Pravas
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2024, 146 (08) : 5543 - 5549
  • [3] Polyhedral Micromotors of Metal-Organic Frameworks: Symmetry Breaking and Propulsion
    Wang, Zhisheng
    Xu, Wei
    Wang, Zuochen
    Lyu, Dengping
    Mu, Yijiang
    Duan, Wendi
    Wang, Yufeng
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2021, 143 (47) : 19881 - 19892
  • [4] Spontaneous asymmetrical crystallization of a three-dimensional diamondoid framework material from achiral precursors
    Chen, Shan-Ci
    Zhang, Jian
    Yu, Rong-Min
    Wu, Xiao-Yuan
    Xie, Yi-Ming
    Wang, Fei
    Lu, Can-Zhong
    CHEMICAL COMMUNICATIONS, 2010, 46 (09) : 1449 - 1451
  • [5] Axially chiral metal-organic frameworks produced from spontaneous resolution with an achiral pyridyl dicarboxylate ligand
    Tan, Xin
    Zhan, Jixian
    Zhang, Jianyong
    Jiang, Long
    Pan, Mei
    Su, Cheng-Yong
    CRYSTENGCOMM, 2012, 14 (01): : 63 - 66
  • [6] Chiral transformations of achiral porous metal-organic frameworks via a stepwise approach
    Yi, Fei-Yan
    Zhang, Jian
    Zhang, Hai-Xia
    Sun, Zhong-Ming
    CHEMICAL COMMUNICATIONS, 2012, 48 (84) : 10419 - 10421
  • [7] Induction of Chirality in a Metal-Organic Framework Built from Achiral Precursors
    Wu, Dong
    Zhou, Kang
    Tian, Jindou
    Liu, Caiping
    Tian, Jiayue
    Jiang, Feilong
    Yuan, Daqiang
    Zhang, Jian
    Chen, Qihui
    Hong, Maochun
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (06) : 3087 - 3094
  • [8] Regulation of Chirality in Metal-Organic Frameworks (MOFs) Based on Achiral Precursors through Substituent Modification
    Gao, Xiang-Jing
    Wu, Ting-Ting
    Ge, Fa-Yuan
    Lei, Ming-Yuan
    Zheng, He-Gen
    INORGANIC CHEMISTRY, 2022, 61 (46) : 18335 - 18339
  • [9] Structured growth of metal-organic frameworks from insoluble precursors
    Walton, Krista
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 257
  • [10] Solvent-Mediated Transformation from Achiral to Chiral Nickel(II) Metal-Organic Frameworks and Reassembly in Solution
    Li, Xiaoju
    Yu, Zhenjiang
    Li, Xinxiong
    Guo, Xiaofang
    CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (46) : 16593 - 16600
12345