Spontaneous symmetry breaking of Co(II) metal-organic frameworks from achiral precursors via asymmetrical crystallization

被引：17
|
作者：
Yu, Ya-Dong
Luo, Chan
Liu, Bao-Yu
Huang, Xiao-Chun [1 ]
Li, Dan
机构：
[1] Shantou Univ, Dept Chem, Guangzhou 515063, Guangdong, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 77期
关键词：
ABSOLUTE CHIRAL INDUCTION; COORDINATION POLYMER; SPONTANEOUS RESOLUTION; ENANTIOSELECTIVE SEPARATION; HOMOCHIRAL CRYSTALLIZATION; MICROPOROUS FRAMEWORK; POLARIZED-LIGHT; CATALYSIS; LIGAND; AMPLIFICATION;
D O I：
10.1039/c5cc06166k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The racemic conglomerate (1P-NH3 + 1M-NH3) and enantioenriched bulk samples (1P-H2O or 1M-NH3) of Co(II) metal-organic frameworks were obtained from achiral precursors under different solvothermal conditions. The bulk homochirality was generated through asymmetrical crystallization in the absence of any chiral additives confirmed by single crystal X-ray diffraction and CD spectroscopy.
引用
收藏
页码：14489 / 14492
页数：4
相关论文
共 50 条
  • [41] Spontaneous resolution and absolute chiral induction of 3d-4f heterometal-organic frameworks from achiral precursors
    Manting Chen
    Zuochang Chen
    Huijun Chen
    Lu Xu
    Xiangjian Kong
    Lasheng Long
    Lansun Zheng
    Science China(Chemistry), 2021, 64 (10) : 1698 - 1702
  • [42] Spontaneous resolution and absolute chiral induction of 3d-4f heterometal-organic frameworks from achiral precursors
    Chen, Manting
    Chen, Zuochang
    Chen, Huijun
    Xu, Lu
    Kong, Xiangjian
    Long, Lasheng
    Zheng, Lansun
    SCIENCE CHINA-CHEMISTRY, 2021, 64 (10) : 1698 - 1702
  • [43] Spontaneous resolution and absolute chiral induction of 3d-4f heterometal-organic frameworks from achiral precursors
    Manting Chen
    Zuochang Chen
    Huijun Chen
    Lu Xu
    Xiangjian Kong
    Lasheng Long
    Lansun Zheng
    Science China(Chemistry), 2021, (10) : 1698 - 1702
  • [44] Metal-organic frameworks derived from imidazolium dicarboxylates and group I and II salts
    Fei, Zhaofu
    Geldbach, Tilmann J.
    Scopelliti, Rosario
    Dyson, Paul J.
    INORGANIC CHEMISTRY, 2006, 45 (16) : 6331 - 6337
  • [45] Study of the reaction mechanisms involved in the formation of zirconium oxycarbide from Metal-Organic Frameworks (MOFs) precursors
    David, Jeremy
    Trolliard, Gilles
    Volkringer, Christophe
    Loiseau, Thierry
    Masson, Olivier
    Maitre, Alexandre
    JOURNAL OF ALLOYS AND COMPOUNDS, 2016, 680 : 571 - 585
  • [46] Near-White Light Emission from Lead(II) Metal-Organic Frameworks
    Peedikakkal, Abdul Malik P.
    Quah, Hong Sheng
    Chia, Stacey
    Jalilov, Almaz S.
    Shaikh, Abdul Rajjak
    Al-Mohsin, Hasan Ali
    Yadava, Khushboo
    Ji, Wei
    Vittal, Jagadese J.
    INORGANIC CHEMISTRY, 2018, 57 (18) : 11341 - 11348
  • [47] An Isoreticular Series of Zinc(II) Metal-Organic Frameworks Derived from Terpyridylcarboxylate Ligands
    Young, David C.
    Yang, Hui
    Telfer, Shane G.
    Kruger, Paul E.
    INORGANIC CHEMISTRY, 2017, 56 (20) : 12224 - 12231
  • [48] Enhanced phosphate removal from water via hierarchically porous metal-organic frameworks
    Wu, Ke
    Zhang, Xiao
    Du, Changwen
    Zhang, Ruimin
    Zhou, Rongyan
    Wang, Shaofeng
    Guan, Ying
    Jiang, Longjie
    Li, Yucong
    Gan, Fangqun
    JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2025, 13 (01):
  • [49] Removal of Pharmaceuticals from Water via π-π Stacking Interactions in Perfluorinated Metal-Organic Frameworks
    DeFuria, Mariah D.
    Zeller, Matthias
    Genna, Douglas T.
    CRYSTAL GROWTH & DESIGN, 2016, 16 (06) : 3530 - 3534
  • [50] Metal-Organic Frameworks for CO2 Separation from Flue and Biogas Mixtures
    Sahoo, Rupam
    Mondal, Supriya
    Mukherjee, Debolina
    Das, Madhab C.
    ADVANCED FUNCTIONAL MATERIALS, 2022, 32 (45)
12345