Regulation of Chirality in Metal-Organic Frameworks (MOFs) Based on Achiral Precursors through Substituent Modification

被引：7

作者：

Gao, Xiang-Jing ^{[1
,2
]}

Wu, Ting-Ting ^{[1
]}

Ge, Fa-Yuan ^{[1
]}

Lei, Ming-Yuan ^{[1
]}

Zheng, He-Gen ^{[1
]}

机构：

[1] Nanjing Univ, Collaborat Innovat Ctr Adv Microstruct, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210023, Peoples R China

[2] China Fire & Rescue Inst, Beijing 102201, Peoples R China

来源：

INORGANIC CHEMISTRY | 2022年 / 61卷 / 46期

基金：

中国国家自然科学基金;

关键词：

INDUCTION;

D O I：

10.1021/acs.inorgchem.2c02745

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The generation and regulation of chirality are closely related to the origin of life. Using achiral precursors to spontaneously build chiral MOFs remains a major challenge. Here, a method to synthesize chiral MOFs from achiral precursors by utilizing chiral fragments was achieved. The transformation from chiral fragments of 1 to chiral frameworks of 2 and 3 was realized by modifying the substituents, and the enantiomer resolution of 3-P41212 and 3-P43212 was achieved by D/L camphoric acid. 3 was then further studied in applications.

引用

页码：18335 / 18339

页数：5

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