Regulation of Chirality in Metal-Organic Frameworks (MOFs) Based on Achiral Precursors through Substituent Modification

被引：7
|
作者：
Gao, Xiang-Jing [1 ,2 ]
Wu, Ting-Ting [1 ]
Ge, Fa-Yuan [1 ]
Lei, Ming-Yuan [1 ]
Zheng, He-Gen [1 ]
机构：
[1] Nanjing Univ, Collaborat Innovat Ctr Adv Microstruct, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210023, Peoples R China
[2] China Fire & Rescue Inst, Beijing 102201, Peoples R China
来源：
INORGANIC CHEMISTRY | 2022年 / 61卷 / 46期
基金：
中国国家自然科学基金;
关键词：
INDUCTION;
D O I：
10.1021/acs.inorgchem.2c02745
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The generation and regulation of chirality are closely related to the origin of life. Using achiral precursors to spontaneously build chiral MOFs remains a major challenge. Here, a method to synthesize chiral MOFs from achiral precursors by utilizing chiral fragments was achieved. The transformation from chiral fragments of 1 to chiral frameworks of 2 and 3 was realized by modifying the substituents, and the enantiomer resolution of 3-P41212 and 3-P43212 was achieved by D/L camphoric acid. 3 was then further studied in applications.
引用
收藏
页码：18335 / 18339
页数：5
相关论文
共 50 条
  • [41] Light induced functionality in metal-organic frameworks (MOFs)
    Allen, Corinne A.
    Tanabe, Kristine K.
    Cohen, Seth M.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 241
  • [42] Exploring metal-organic frameworks (MOFs) for catalysis and separation
    SonBinh Nguyen
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 257
  • [43] Conductive metal-organic frameworks (MOFs) for electrocatalytic applications
    Marinescu, Smaranda
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 256
  • [44] Green metal-organic frameworks (MOFs) for biomedical applications
    Rabiee, Navid
    Atarod, Monireh
    Tavakolizadeh, Maryam
    Asgari, Shadi
    Rezaei, Mohsen
    Akhavan, Omid
    Pourjavadi, Ali
    Jouyandeh, Maryam
    Lima, Eder C.
    Mashhadzadeh, Amin Hamed
    Ehsani, Ali
    Ahmadi, Sepideh
    Saeb, Mohammad Reza
    MICROPOROUS AND MESOPOROUS MATERIALS, 2022, 335
  • [45] Efficient carbon capture in metal-organic frameworks (MOFs)
    Yildirim, Taner
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 243
  • [46] Recent progress in metal-organic frameworks (MOFs) for electrocatalysis
    Li, Cha
    Zhang, Hao
    Liu, Ming
    Lang, Fei-Fan
    Pang, Jiandong
    Bu, Xian-He
    Industrial Chemistry and Materials, 2023, 1 (01): : 9 - 38
  • [47] Wastewater treatment using Metal-Organic Frameworks (MOFs)
    Manzoor, Muhammad Husnain
    Naz, Namisa
    Naqvi, Syyeda Maimoona Ghayyoor
    Ashraf, Shumaila
    Ashiq, Muhammad Zain
    Verpoort, Francis
    APPLIED MATERIALS TODAY, 2024, 40
  • [48] A collection of forcefield precursors for metal-organic frameworks
    Chen, Taoyi
    Manz, Thomas A.
    RSC ADVANCES, 2019, 9 (63) : 36492 - 36507
  • [49] Metal-organic frameworks (MOFs) based nanofiber architectures for the removal of heavy metal ions
    Adil, Heja Ibrahim
    Thalji, Mohammad R.
    Yasin, Suhad A.
    Saeed, Ibtisam A.
    Assiri, Mohammed A.
    Chong, Kwok Feng
    Ali, Gomaa A. M.
    RSC ADVANCES, 2022, 12 (03) : 1433 - 1450
  • [50] Aromatic Substituent Effects on the Flexibility of Metal-Organic Frameworks
    Hahm, Hyungwoo
    Yoo, Kwangho
    Ha, Hyeonbin
    Kim, Min
    INORGANIC CHEMISTRY, 2016, 55 (15) : 7576 - 7581
12345