Cationic complexes with chiral diamine or dithiourea ligands as catalysts for molecular asymmetric hydrogenation

被引：35
|
作者：
Tommasino, ML
Thomazeau, C
Touchard, F
Lemaire, M
机构：
[1] CNRS, CPE, Inst Rech Catalyse, F-69622 Villeurbanne, France
[2] CNRS, CPE, Lab Catalyse & Synthese Organ, F-69622 Villeurbanne, France
来源：
TETRAHEDRON-ASYMMETRY | 1999年 / 10卷 / 09期
关键词：
D O I：
10.1016/S0957-4166(99)00173-1
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The asymmetric reduction of phenylglyoxylate methyl ester with molecular hydrogen and catalytic amounts of cationic chiral diamine and dithiourea complexes of rhodium and iridium is reported. The catalytic activity of the complexes is rather different if the C-2-symmetric ligand is a diamine or a dithiourea, even if enantioselectivity is always observed, with ee values up to 72%. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：1813 / 1819
页数：7
相关论文
共 50 条
  • [41] Synthesis of a water-soluble cationic chiral diamine ligand bearing a diguanidinium and application in asymmetric transfer hydrogenation
    Tang, Yuanfu
    Li, Xuefeng
    Lian, Chunxia
    Zhu, Jin
    Deng, Jingen
    TETRAHEDRON-ASYMMETRY, 2011, 22 (14-15) : 1530 - 1535
  • [42] Asymmetric Hydrogenation of Ketones——Design of Chiral Catalysts
    Takeshi Ohkuma
    复旦学报(自然科学版), 2005, (05) : 152 - 153
  • [43] CHIRAL RHODIUM CARBOXYLATES AS ASYMMETRIC HYDROGENATION CATALYSTS
    BHADURI, S
    KHWAJA, H
    PROCEEDINGS OF THE INDIAN ACADEMY OF SCIENCES-CHEMICAL SCIENCES, 1994, 106 (04): : 847 - 855
  • [44] Toward efficient asymmetric hydrogenation: Architectural and functional engineering of chiral molecular catalysts
    Noyori, R
    Kitamura, M
    Ohkuma, T
    PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2004, 101 (15) : 5356 - 5362
  • [45] CATALYTIC ASYMMETRIC HYDROGENATION USING RUTHENIUM(II) COMPLEXES WITH CHELATING CHIRAL SULFOXIDE LIGANDS
    JAMES, BR
    MCMILLAN, RS
    CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1977, 55 (22): : 3927 - 3932
  • [46] ASYMMETRIC HYDROGENATION BY HOMOGENEOUS AND HETEROGENIZED RHODIUM(I) COMPLEXES WITH CHIRAL PHOSPHINE-LIGANDS
    KINTING, A
    KRAUSE, HW
    ZEITSCHRIFT FUR CHEMIE, 1988, 28 (07): : 266 - 266
  • [47] Asymmetric transfer hydrogenation of prochiral ketones catalyzed by chiral ruthenium complexes with aminophosphine ligands
    Gao, JX
    Xu, PP
    Yi, XD
    Yang, CB
    Zhang, H
    Cheng, SH
    Wan, HL
    Tsai, KR
    Ikariya, T
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 147 (1-2) : 105 - 111
  • [48] Iridium and rhodium complexes with the planar chiral thioether ligands in asymmetric hydrogenation of ketones and imines
    Kozinets, E. M.
    Silantyev, G. A.
    Belkova, N. V.
    Shubina, E. S.
    Poli, R.
    Manoury, E.
    RUSSIAN CHEMICAL BULLETIN, 2013, 62 (03) : 751 - 757
  • [49] Rhodium cationic complexes using macrocyclic diphosphines as chiral ligands:: Application in asymmetric hydroformylation
    Pàmies, O
    Net, G
    Widhalm, M
    Ruiz, A
    Claver, C
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 587 (01) : 136 - 143
  • [50] Chiral complexes of transition metals with chelating nitrogen ligands in asymmetric hydrogenation with hydrogen transfer
    Badyrova, Nataliya M.
    Nindakova, Lidiya O.
    IZVESTIYA VUZOV-PRIKLADNAYA KHIMIYA I BIOTEKHNOLOGIYA, 2019, 9 (04): : 621 - 634
12345