Cationic complexes with chiral diamine or dithiourea ligands as catalysts for molecular asymmetric hydrogenation

被引：35
|
作者：
Tommasino, ML
Thomazeau, C
Touchard, F
Lemaire, M
机构：
[1] CNRS, CPE, Inst Rech Catalyse, F-69622 Villeurbanne, France
[2] CNRS, CPE, Lab Catalyse & Synthese Organ, F-69622 Villeurbanne, France
来源：
TETRAHEDRON-ASYMMETRY | 1999年 / 10卷 / 09期
关键词：
D O I：
10.1016/S0957-4166(99)00173-1
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The asymmetric reduction of phenylglyoxylate methyl ester with molecular hydrogen and catalytic amounts of cationic chiral diamine and dithiourea complexes of rhodium and iridium is reported. The catalytic activity of the complexes is rather different if the C-2-symmetric ligand is a diamine or a dithiourea, even if enantioselectivity is always observed, with ee values up to 72%. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：1813 / 1819
页数：7
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