17O NMR study of the triangular lattice antiferromagnet CuCrO2

被引:6
|
作者
Ogloblichev, Vasily V. [1 ,2 ,3 ]
Smolnikov, Alexey G. [1 ]
Sadykov, Almaz F. [1 ]
Piskunov, Yuri V. [1 ]
Gerashenko, Alexander P. [1 ]
Furukawa, Yuji [2 ,3 ]
Kumagai, Ken-ichi [3 ]
Yakubovsky, Andrey Yu. [4 ]
Mikhalev, Konstantin N. [1 ]
Barilo, Sergei N. [5 ]
Shiryaev, Sergei V. [5 ]
Belozerov, Alexander S. [1 ]
机构
[1] Russian Acad Sci, Ural Branch, MN Mikheev Inst Met Phys, 18 S Kovalevskaya St, Ekaterinburg 620108, Russia
[2] Iowa State Univ, Dept Phys & Astron, Ames Lab, Ames, IA 50011 USA
[3] Hokkaido Univ, Fac Sci, Dept Phys, Sapporo, Hokkaido 0600810, Japan
[4] Kurchatov Inst, Natl Res Ctr, Moscow 123182, Russia
[5] Natl Acad Sci Belarus, Inst Solid State Phys & Semicond, Minsk 220072, BELARUS
基金
俄罗斯科学基金会;
关键词
O-17; NMR; Electric field gradient; Frustrated systems; Helicoidal magnetic structure; SPIN; RESONANCE;
D O I
10.1016/j.jmmm.2018.02.080
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The single crystalline and powder samples of multiferroic CuCrO2 have been investigated by O-17 NMR techniques in the paramagnetic and magnetically ordered states. The unusual negative hyperfine field on oxygen nuclei, H-hf = -5.2 kOe/mu B, has been determined in paramagnetic state. The O-17 NMR spectrum in ordered state has a shape typical for incommensurate magnetic structure. It can be well described taking into account only dipole fields which are produced by Cr3+- ions with magnetic moment mu = 2.2 mu(B). The parameters of the EFG (electric field gradient) tensor - the quadrupole frequency (upsilon(Q)) and the asymmetry parameter, have been determined. The value of upsilon(Q) increases monotonously with decreasing temperature in the range 90 K > T > 1.5 K. The estimates of the population of the ligands p - orbitals have been obtained. (C) 2018 Elsevier B.V. All rights reserved.
引用
收藏
页码:1 / 9
页数:9
相关论文
共 50 条
  • [31] 17O NMR study on YBa2Cu4O8
    Machi, T
    Koshizuka, N
    Yasuoka, H
    PHYSICA B, 2000, 284 : 943 - 944
  • [32] NMR of enaminones: Part 4 - 17O NMR study of 2,2-diacylenamines
    Zhuo, Jin-Cong
    1997, John Wiley and Sons Ltd (35)
  • [33] 17O NMR studies of sodalites
    Loeser, T
    Freude, D
    Mabande, GTP
    Schwieger, W
    CHEMICAL PHYSICS LETTERS, 2003, 370 (1-2) : 32 - 38
  • [34] 17O NMR of borophosphate glasses
    Zeyer, M
    Montagne, L
    Jäger, C
    GLASS SCIENCE AND TECHNOLOGY, 2002, 75 : 186 - 190
  • [35] 17O NMR spectra of α-diesters
    Cerioni, G
    Uccheddu, G
    MAGNETIC RESONANCE IN CHEMISTRY, 2006, 44 (02) : 118 - 120
  • [36] 17O NMR studies on α-diamides
    Cerioni, G
    Giumanini, AG
    Verardo, G
    JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 1998, 11 (06) : 387 - 391
  • [37] A detailed study of the magnetic phase transition in CuCrO2
    Ehlers, G.
    Podlesnyak, A. A.
    Frontzek, M.
    Freitas, R. S.
    Ghivelder, L.
    Gardner, J. S.
    Shiryaev, S. V.
    Barilo, S.
    JOURNAL OF PHYSICS-CONDENSED MATTER, 2013, 25 (49)
  • [38] 17O NMR study of chromium(VI) ions in water
    J Am Chem Soc, 34 (7969):
  • [39] 17O NMR study in YBa2Cu3O7-y
    Kohori, Y., 1600, (90 pt 91):
  • [40] 17O NMR study in (Pu0.91Am0.09)O2
    Tokunaga, Yo
    Osaka, Masahiko
    Kambe, Shinsaku
    Miwa, Shuhei
    Sakai, Hironori
    Chudo, Hiroyuki
    Homma, Yoshiya
    Shiokawa, Yoshinobu
    JOURNAL OF NUCLEAR MATERIALS, 2010, 396 (01) : 107 - 111