New Horizons in Chemical Functionalization of Endohedral Metallofullerenes

被引：17

作者：

Yamada, Michio ^{[1
]}

Liu, Michael T. H. ^{[2
]}

Nagase, Shigeru ^{[3
]}

Akasaka, Takeshi ^{[1
,4
,5
,6
]}

机构：

[1] Tokyo Gakugei Univ, Dept Chem, Koganei, Tokyo 1848501, Japan

[2] Univ Prince Edward Isl, Dept Chem, Charlottetown, PE C1A 4P3, Canada

[3] Kyoto Univ, Fukui Inst Fundamental Chem, Sakyo Ku, Kyoto 6068103, Japan

[4] Univ Tsukuba, TARA Ctr, Tsukuba, Ibaraki 3058577, Japan

[5] Fdn Adv Int Sci, Tsukuba, Ibaraki 3050821, Japan

[6] Huazhong Univ Sci & Technol, Sch Mat Sci & Engn, State Key Lab Mat Proc & Dye & Mold Tech, Wuhan 430074, Peoples R China

来源：

MOLECULES | 2020年 / 25卷 / 16期

关键词：

addition reactions; carbenes; chemical functionalization; electrochemistry; endohedral metallofullerene; fullerene; lanthanide ions; nanocarbon; pericyclic reactions; radicals; LEWIS-ACID; CRYSTALLOGRAPHIC CHARACTERIZATION; EXOHEDRAL FUNCTIONALIZATION; METAL ATOMS; FULLERENE; REACTIVITY; ADDUCTS; C-60; CARBENE; ISOMERS;

D O I：

10.3390/molecules25163626

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

This overview explains some new aspects of chemical functionalization of endohedral metallofullerenes (EMFs) that have been unveiled in recent years. After differences in chemical reactivity between EMFs and the corresponding empty fullerenes are discussed, cage-opening reactions of EMFs are examined. Then, the selective bisfunctionalization of EMFs is explained. Finally, single-bonding derivatization of EMFs is addressed. The diversity and applicability of the chemical functionalization of endohedral metallofullerenes are presented to readers worldwide.

引用

页数：14

共 50 条

[41] Structural and electronic properties of endohedral metallofullerenes
Akasaka, Takeshi
Lu, Xing
CHEMICAL RECORD, 2012, 12 (02): : 256 - 269
[42] Recent progress in the chemistry of endohedral metallofullerenes
Lu, Xing
Bao, Lipiao
Akasaka, Takeshi
Nagase, Shigeru
CHEMICAL COMMUNICATIONS, 2014, 50 (94) : 14701 - 14715
[43] Magnetic anisotropy of cerium endohedral metallofullerenes
Inakuma, M
Kato, H
Taninaka, A
Shinohara, H
Enoki, T
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (29): : 6965 - 6973
[44] Endohedral metallofullerenes and nano-peapods
Kitaura, Ryo
Shinohara, Hisanori
Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers, 2007, 46 (3 A): : 881 - 891
[45] Chemistry of endohedral metallofullerenes: the role of metals
Lu, Xing
Akasaka, Takeshi
Nagase, Shigeru
CHEMICAL COMMUNICATIONS, 2011, 47 (21) : 5942 - 5957
[46] Organic approaches to endohedral metallofullerenes.
Rubin, Y
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 215 : U43 - U43
[47] Chemical Reactions of Cationic Metallofullerenes: An Alternative Route for Exohedral Functionalization
Hu, Yajing
Sole-Daura, Albert
Yao, Yang-Rong
Liu, Xuechen
Liu, Sijie
Yu, Ao
Peng, Ping
Poblet, Josep M.
Rodriguez-Fortea, Antonio
Echegoyen, Luis
Li, Fang-Fang
CHEMISTRY-A EUROPEAN JOURNAL, 2020, 26 (08) : 1748 - 1753
[48] Endohedral metallofullerenes based on some missing fullerenes
Wang, CR
Dennis, TJS
Itho, T
Ogawa, T
Shinohara, H
RECENT ADVANCES IN THE CHEMISTRY AND PHYSICS OF FULLERENES AND RELATED MATERIAL, VOL 7, 1999, 99 (12): : 795 - 805
[49] Synthesis of High Yield of Higher Endohedral Metallofullerenes
Li Nan
Liu Jia
Shi Zu-Jin
Xu Shu-Kun
Gu Zhen-Nan
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2009, 30 (07): : 1284 - 1286
[50] Mri contrast agents by endohedral metallofullerenes.
Shinohara, H
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 223 : U661 - U661

← 1 2 3 4 5 →