New Horizons in Chemical Functionalization of Endohedral Metallofullerenes

被引：17

作者：

Yamada, Michio ^{[1
]}

Liu, Michael T. H. ^{[2
]}

Nagase, Shigeru ^{[3
]}

Akasaka, Takeshi ^{[1
,4
,5
,6
]}

机构：

[1] Tokyo Gakugei Univ, Dept Chem, Koganei, Tokyo 1848501, Japan

[2] Univ Prince Edward Isl, Dept Chem, Charlottetown, PE C1A 4P3, Canada

[3] Kyoto Univ, Fukui Inst Fundamental Chem, Sakyo Ku, Kyoto 6068103, Japan

[4] Univ Tsukuba, TARA Ctr, Tsukuba, Ibaraki 3058577, Japan

[5] Fdn Adv Int Sci, Tsukuba, Ibaraki 3050821, Japan

[6] Huazhong Univ Sci & Technol, Sch Mat Sci & Engn, State Key Lab Mat Proc & Dye & Mold Tech, Wuhan 430074, Peoples R China

来源：

MOLECULES | 2020年 / 25卷 / 16期

关键词：

addition reactions; carbenes; chemical functionalization; electrochemistry; endohedral metallofullerene; fullerene; lanthanide ions; nanocarbon; pericyclic reactions; radicals; LEWIS-ACID; CRYSTALLOGRAPHIC CHARACTERIZATION; EXOHEDRAL FUNCTIONALIZATION; METAL ATOMS; FULLERENE; REACTIVITY; ADDUCTS; C-60; CARBENE; ISOMERS;

D O I：

10.3390/molecules25163626

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

This overview explains some new aspects of chemical functionalization of endohedral metallofullerenes (EMFs) that have been unveiled in recent years. After differences in chemical reactivity between EMFs and the corresponding empty fullerenes are discussed, cage-opening reactions of EMFs are examined. Then, the selective bisfunctionalization of EMFs is explained. Finally, single-bonding derivatization of EMFs is addressed. The diversity and applicability of the chemical functionalization of endohedral metallofullerenes are presented to readers worldwide.

引用

页数：14

共 50 条

[21] Chemical oxidation of endohedral metallofullerenes: identification and separation of distinct classes
Bolskar, RD
Alford, JM
CHEMICAL COMMUNICATIONS, 2003, (11) : 1292 - 1293
[22] New method for the macroscopic preparation of endohedral metallofullerenes.
Jung, DY
Porter, LA
Lee, TR
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 215 : U837 - U837
[23] Spectroscopic studies of endohedral metallofullerenes
Kodama, T
Kusuda, M
Ozawa, N
Fujii, R
Sakaguchi, K
Nishikawa, H
Ikemoto, I
Kikuchi, K
Miyake, Y
Achiba, Y
NEW DIAMOND AND FRONTIER CARBON TECHNOLOGY, 2001, 11 (06): : 367 - 373
[24] Endohedral metallofullerenes in carbon nanotubes
Okazaki, T
Inoue, T
Wang, ZW
Shinohara, H
Suenaga, K
Hirahara, K
Bandow, S
Iijima, S
Lian, YF
Gu, ZN
FULLERENES FOR THE NEW MILLENNIUM, 2001, 2000 (11): : 349 - 353
[25] Unconventional structures of endohedral metallofullerenes
Kobayashi, K
Nagase, S
RECENT ADVANCES IN THE CHEMISTRY AND PHYSICS OF FULLERENES AND RELATED MATERIALS, VOL 6, 1998, 98 (08): : 981 - 989
[26] Enantioselective Synthesis of Endohedral Metallofullerenes
Sawai, Koji
Takano, Yuta
Izquierdo, Marta
Filippone, Salvatore
Martin, Nazario
Slanina, Zdenek
Mizorogi, Naomi
Waelchli, Markus
Tsuchiya, Takahiro
Akasaka, Takeshi
Nagase, Shigeru
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (44) : 17746 - 17752
[27] Endohedral metallofullerenes: New spherical cage molecules with interesting properties
Nagase, S
Kobayashi, K
Akasaka, T
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1996, 69 (08) : 2131 - 2142
[28] New characterization of lanthanum- and scandium-endohedral metallofullerenes
Shinohara, Hisanori
Yamaguchi, Hiroki
Hayashi, Naoyuki
Sato, Hiroyasu
Inagaki, Motoki
Saito, Yahachi
Bandow, Shunji
Kitagawa, Hiroshi
Mitani, Tadaoki
Inokuchi, Hiroo
Materials science & engineering. B, Solid-state materials for advanced technology, 1993, B19 (1-2): : 25 - 30
[29] Trifluoromethyl derivatives of cerium endohedral metallofullerenes
Kareev, I. E.
Bubnov, V. P.
Yagubskii, E. B.
RUSSIAN CHEMICAL BULLETIN, 2011, 60 (06) : 1058 - 1062
[30] Magnetic endohedral metallofullerenes with floppy interiors
Qian, Meichun
Ong, Stephen V.
Khanna, Shiv N.
Knickelbein, Mark B.
PHYSICAL REVIEW B, 2007, 75 (10)

← 1 2 3 4 5 →