New Horizons in Chemical Functionalization of Endohedral Metallofullerenes

被引：17

作者：

Yamada, Michio ^{[1
]}

Liu, Michael T. H. ^{[2
]}

Nagase, Shigeru ^{[3
]}

Akasaka, Takeshi ^{[1
,4
,5
,6
]}

机构：

[1] Tokyo Gakugei Univ, Dept Chem, Koganei, Tokyo 1848501, Japan

[2] Univ Prince Edward Isl, Dept Chem, Charlottetown, PE C1A 4P3, Canada

[3] Kyoto Univ, Fukui Inst Fundamental Chem, Sakyo Ku, Kyoto 6068103, Japan

[4] Univ Tsukuba, TARA Ctr, Tsukuba, Ibaraki 3058577, Japan

[5] Fdn Adv Int Sci, Tsukuba, Ibaraki 3050821, Japan

[6] Huazhong Univ Sci & Technol, Sch Mat Sci & Engn, State Key Lab Mat Proc & Dye & Mold Tech, Wuhan 430074, Peoples R China

来源：

MOLECULES | 2020年 / 25卷 / 16期

关键词：

addition reactions; carbenes; chemical functionalization; electrochemistry; endohedral metallofullerene; fullerene; lanthanide ions; nanocarbon; pericyclic reactions; radicals; LEWIS-ACID; CRYSTALLOGRAPHIC CHARACTERIZATION; EXOHEDRAL FUNCTIONALIZATION; METAL ATOMS; FULLERENE; REACTIVITY; ADDUCTS; C-60; CARBENE; ISOMERS;

D O I：

10.3390/molecules25163626

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

This overview explains some new aspects of chemical functionalization of endohedral metallofullerenes (EMFs) that have been unveiled in recent years. After differences in chemical reactivity between EMFs and the corresponding empty fullerenes are discussed, cage-opening reactions of EMFs are examined. Then, the selective bisfunctionalization of EMFs is explained. Finally, single-bonding derivatization of EMFs is addressed. The diversity and applicability of the chemical functionalization of endohedral metallofullerenes are presented to readers worldwide.

引用

页数：14

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