High Performance Sn-In Cathode for the Electrochemical Reduction of Carbon Dioxide to Formic Acid

被引：6

作者：

Li, Fajun ^{[1
,2
]}

Zhang, Hua ^{[1
]}

Ji, Shuai ^{[1
]}

Liu, Wei ^{[3
]}

Zhang, Dong ^{[1
]}

Zhang, Chengdu ^{[1
]}

Yang, Jing ^{[1
]}

Yang, Fei ^{[1
]}

Lei, Lixu ^{[1
,2
]}

机构：

[1] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Jiangsu, Peoples R China

[2] Jiangsu Key Lab Adv Metall Mat, Nanjing 211189, Jiangsu, Peoples R China

[3] Shuangdeng Grp Co Ltd, Key Lab Electrochem Energy Storage Technol Jiangs, Taizhou 225300, Jiangsu, Peoples R China

来源：

INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE | 2019年 / 14卷 / 05期

关键词：

Electrochemical reduction; carbon dioxide; formate; tin-indium bimetallic catalyst; space time yield; PHOTOELECTRON-SPECTROSCOPY; METAL-ELECTRODES; CO2; REDUCTION; FORMATE; SELECTIVITY; EFFICIENCY; CONVERSION; CATALYSTS; ALLOY;

D O I：

10.20964/2019.05.44

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Both Sn and In have been potentiostatically co-deposited on the surface of Cu foam at different potentials to prepare Sn-In bimetallic electrodes. Among them, the Sn42In58 electrode has excellent catalytic activity towards CO2 reduction to formic acid. At -1.6 V versus Ag/AgCl, the formate Faradaic efficiency reaches its maximum, 88%; and its space time yield reaches 309 mu mol h(-1) cm(-2) at -1.8 V versus Ag/AgCl. When it is used in the biomimetic electrochemical cell reported previously by us, a much higher space time yield, 468 mu mol h(-1) cm(-2) is obtained.

引用

页码：4161 / 4172

页数：12

共 50 条

[21] THE REDUCTION OF CARBON DIOXIDE TO FORMIC ACID WITH LITHIUM ALUMINUM HYDRIDE
FINHOLT, AE
JACOBSON, EC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1952, 74 (15) : 3943 - 3944
[22] Formic Acid Formation from the Electrochemical Reduction of Carbon Dioxide Catalyzed by a Rhodium Protoporphyrin in aqueous solution
Shen, Jing
Deng, Kunxiang
Li, Xiangjun
Lan, Donghui
Fang, Zhengjun
[J]. INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2021, 16 (09): : 1 - 11
[23] Selective electrochemical reduction of carbon dioxide to formic acid using indium-zinc bimetallic nanocrystals
Kwon, Ik Seon
Debela, Tekalign Terfa
Kwak, In Hye
Seo, Hee Won
Park, Kidong
Kim, Doyeon
Yoo, Seung Jo
Kim, Jin-Gyu
Park, Jeunghee
Kang, Hong Seok
[J]. JOURNAL OF MATERIALS CHEMISTRY A, 2019, 7 (40) : 22879 - 22883
[24] THE ELECTROCHEMICAL CONVERSION OF CARBON-DIOXIDE INTO METHANOL - THE FORMIC-ACID REDUCTION STEP IN ACIDIC SOLUTIONS
MILES, MH
FLETCHER, AN
MCMANIS, GE
SPREER, LO
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1985, 190 (1-2) : 157 - 170
[25] CARBON-DIOXIDE FIXATION BY ELECTROLYSIS OF AQUEOUS HYDROGENCARBONATE SOLUTION - REDUCTION TO FORMIC-ACID AT A MERCURY CATHODE
FUJIWARA, H
KONNO, A
NONAKA, T
[J]. CHEMISTRY LETTERS, 1991, (10) : 1843 - 1846
[26] Assessing the Influence of Supercritical Carbon Dioxide on the Electrochemical Reduction to Formic Acid Using Carbon-Supported Copper Catalysts
Puring, Kai Junge
Evers, Olga
Prokein, Michael
Siegmund, Daniel
Scholten, Fabian
Moelders, Nils
Renner, Manfred
Roldan Cuenya, Beatriz
Petermann, Marcus
Weidner, Eckhard
Apfel, Ulf-Peter
[J]. ACS CATALYSIS, 2020, 10 (21) : 12783 - 12789
[27] Conversion of carbon dioxide to methanol through the reduction of formic acid on chromium
Kotoulas, Ioannis
Kyriacou, Georgios
[J]. JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2017, 92 (07) : 1794 - 1800
[28] Sustainable production of formic acid by electrolytic reduction of gaseous carbon dioxide
Lee, Seunghwa
Ju, HyungKuk
Machunda, Revocatus
Uhm, Sunghyun
Lee, Jae Kwang
Lee, Hye Jin
Lee, Jaeyoung
[J]. JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (06) : 3029 - 3034
[29] Electrochemical Reduction of Carbon Dioxide to Formic Acid in Ionic Liquid [Emim][N(CN)2]/Water System
Zhang, Xiangjing
Zhao, Ying
Hu, Shuozhen
Gliege, Marisa Elise
Liu, Yumin
Liu, Runjing
Scudiero, Louis
Hu, Yongqi
Ha, Su
[J]. ELECTROCHIMICA ACTA, 2017, 247 : 281 - 287
[30] One-step co-electrodeposition of SnBi for efficient electrochemical reduction of carbon dioxide to formic acid
Yang, Shuaipeng
Sun, Yuan
Wang, Chunlai
Lv, Li
Hu, Mengxiang
Jin, Junsu
Xie, Hangxin
[J]. CATALYSIS SCIENCE & TECHNOLOGY, 2023, 13 (03) : 758 - 766

← 1 2 3 4 5 →