A carbazole-based conjugated polymer bearing ruthenium complexes, synthesis and preliminary photovoltaic study

被引：2

作者：

Wang, Yanrong ^{[1
]}

Zheng, Hongjuan ^{[1
]}

Xu, Shengang ^{[2
]}

Li, Yaping ^{[1
]}

Cao, Shaokui ^{[2
]}

机构：

[1] Henan Univ Technol, Sch Mat Sci & Engn, Zhengzhou 450001, Peoples R China

[2] Zhengzhou Univ, Sch Mat Sci & Engn, Zhengzhou 450052, Peoples R China

来源：

ADVANCED MANUFACTURING TECHNOLOGY AND SYSTEMS | 2012年 / 159卷

基金：

中国国家自然科学基金;

关键词：

carbazole; conjugated polymer; ruthenium complex; photovoltaic material; SOLAR-CELLS; POLYCARBAZOLES;

D O I：

10.4028/www.scientific.net/AMM.159.6

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A carbazole-based conjugated polymer bearing ruthenium complexes Pbpy(Ru)-Cz was synthesized aiming to obtain a material with dual functionalities of both light absorption and hole-transport for photovoltaic cells. Chemical structures of the monomers and polymers were confirmed by H-1 NMR, IR, and elemental analysis. Pbpy(Ru)-Cz showed good thermal stability and solubility. The absorption spectrum of Pbpy(Ru)-Cz showed a broader peak covering the wavelength range from 380 to 650 nm. Preliminary photovoltaic behavior was evaluated by fabricating photovoltaic cells. As measured under a 55 mW cm(-2) compact white arc lamp, V-OC, J(SC), FF and eta(e) of the device ITO/Pbpy(Ru)-Cz:PCBM/A1 were 0.18 V, 0.019 mA cm(-2), 0.22 and 1.40x10(-3)%, respectively.

引用

页码：6 / +

页数：2

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