A carbazole-based conjugated polymer bearing ruthenium complexes, synthesis and preliminary photovoltaic study

被引：2
|
作者：
Wang, Yanrong [1 ]
Zheng, Hongjuan [1 ]
Xu, Shengang [2 ]
Li, Yaping [1 ]
Cao, Shaokui [2 ]
机构：
[1] Henan Univ Technol, Sch Mat Sci & Engn, Zhengzhou 450001, Peoples R China
[2] Zhengzhou Univ, Sch Mat Sci & Engn, Zhengzhou 450052, Peoples R China
来源：
ADVANCED MANUFACTURING TECHNOLOGY AND SYSTEMS | 2012年 / 159卷
基金：
中国国家自然科学基金;
关键词：
carbazole; conjugated polymer; ruthenium complex; photovoltaic material; SOLAR-CELLS; POLYCARBAZOLES;
D O I：
10.4028/www.scientific.net/AMM.159.6
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A carbazole-based conjugated polymer bearing ruthenium complexes Pbpy(Ru)-Cz was synthesized aiming to obtain a material with dual functionalities of both light absorption and hole-transport for photovoltaic cells. Chemical structures of the monomers and polymers were confirmed by H-1 NMR, IR, and elemental analysis. Pbpy(Ru)-Cz showed good thermal stability and solubility. The absorption spectrum of Pbpy(Ru)-Cz showed a broader peak covering the wavelength range from 380 to 650 nm. Preliminary photovoltaic behavior was evaluated by fabricating photovoltaic cells. As measured under a 55 mW cm(-2) compact white arc lamp, V-OC, J(SC), FF and eta(e) of the device ITO/Pbpy(Ru)-Cz:PCBM/A1 were 0.18 V, 0.019 mA cm(-2), 0.22 and 1.40x10(-3)%, respectively.
引用
收藏
页码：6 / +
页数：2
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