INTERMOLECULAR HYDROAMINATION OF STYRENE CATALYZED BY PALLADIUM(II) N-HETEROCYCLIC CARBENE COMPLEXES IN IONIC LIQUID

被引：8
|
作者：
Yigit, Beyhan [1 ]
Yigit, Murat [1 ]
Gok, Yetkin [2 ]
Celikal, Ozlem Ozeroglu [2 ]
机构：
[1] Adiyaman Univ, Fac Sci & Art, Dept Chem, TR-02040 Adiyaman, Turkey
[2] Inonu Univ, Fac Sci & Art, Dept Chem, TR-44260 Malatya, Turkey
来源：
HETEROCYCLES | 2016年 / 92卷 / 11期
关键词：
INTRAMOLECULAR HYDROAMINATION; ASYMMETRIC HYDROAMINATION; UNACTIVATED ALKENES; LIGANDS SYNTHESIS; DIRECT ADDITION; SILVER(I); AMINATION; ANILINE; OLEFINS; ALKYNES;
D O I：
10.3987/COM-16-13546
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
PdCl2(NHC)(2) complexes have been synthesized by the reaction of palladium acetate with a series of benzimidazolium and imidazolinium salts and characterized by elemental analysis, H-1 NMR and C-13 NMR spectroscopy. These complexes were used as catalysts for the intermolecular hydroamination reactions between styrene with various anilines in ionic liquid at 160 degrees C and corresponding anti-Markovnikov products were obtained with a selectivity of 100% in good yields.
引用
收藏
页码：1994 / 2003
页数：10
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