INTERMOLECULAR HYDROAMINATION OF STYRENE CATALYZED BY PALLADIUM(II) N-HETEROCYCLIC CARBENE COMPLEXES IN IONIC LIQUID

被引：8

作者：

Yigit, Beyhan ^{[1
]}

Yigit, Murat ^{[1
]}

Gok, Yetkin ^{[2
]}

Celikal, Ozlem Ozeroglu ^{[2
]}

机构：

[1] Adiyaman Univ, Fac Sci & Art, Dept Chem, TR-02040 Adiyaman, Turkey

[2] Inonu Univ, Fac Sci & Art, Dept Chem, TR-44260 Malatya, Turkey

来源：

HETEROCYCLES | 2016年 / 92卷 / 11期

关键词：

INTRAMOLECULAR HYDROAMINATION; ASYMMETRIC HYDROAMINATION; UNACTIVATED ALKENES; LIGANDS SYNTHESIS; DIRECT ADDITION; SILVER(I); AMINATION; ANILINE; OLEFINS; ALKYNES;

D O I：

10.3987/COM-16-13546

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

PdCl2(NHC)(2) complexes have been synthesized by the reaction of palladium acetate with a series of benzimidazolium and imidazolinium salts and characterized by elemental analysis, H-1 NMR and C-13 NMR spectroscopy. These complexes were used as catalysts for the intermolecular hydroamination reactions between styrene with various anilines in ionic liquid at 160 degrees C and corresponding anti-Markovnikov products were obtained with a selectivity of 100% in good yields.

引用

页码：1994 / 2003

页数：10

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