Hydrofunctionalization of Olefins to Higher Aliphatic Alcohols via Visible-Light Photocatalytic Coupling

被引：3

作者：

Bao, Jingxian ^{[1
,2
]}

Fan, Yonghui ^{[2
]}

Zhang, Shuyi ^{[2
,3
]}

Zhong, Liangshu ^{[2
,4
]}

Wu, Minghong ^{[5
]}

Sun, Yuhan ^{[2
,4
]}

机构：

[1] Shanghai Univ, Dept Chem, Coll Sci, Shanghai 200444, Peoples R China

[2] Chinese Acad Sci, Shanghai Adv Res Inst, Key Lab Low Carbon Convers Sci & Engn, Shanghai 201203, Peoples R China

[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

[4] ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China

[5] Shanghai Univ, Shanghai 200444, Peoples R China

来源：

CATALYSIS LETTERS | 2019年 / 149卷 / 06期

基金：

国家重点研发计划;

关键词：

ETHYLENE-GLYCOL; PHASE JUNCTION; HYDROFORMYLATION; FORMALDEHYDE; HYDROGEN; METHANOL; CONSTRUCTION; ALKYLATION; CONVERSION; MECHANISM;

D O I：

10.1007/s10562-019-02737-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An atomically economical green protocol for the hydrofunctionalization of olefins to higher aliphatic alcohols with 100% anti-Markovnikov regioselectivity was developed via visible-light photocatalytic coupling. This method employs cheap, readily available and abundant methanol as both the C1 feedstock and the hydrogen source under visible light irradiation over CdS photocatalyst. A wide scope of olefin substrates could be hydrofunctionalized successfully to the corresponding higher alcohols with high selectivity. Besides alcohol, acetone and acetonitrile can also couple with olefins to generate the corresponding hydrofunctionalization products, suggesting promising potential industrial application. [GRAPHICS] .

引用

页码：1651 / 1659

页数：9

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