Visible-Light Photocatalysis of the Ketyl Radical Coupling Reaction

被引：107
|
作者：
Xia, Qing [1 ]
Dong, Jianyang [1 ]
Song, Hongjian [1 ]
Wang, Qingmin [1 ,2 ]
机构：
[1] Nankai Univ, Coll Chem, Res Inst Elementoorgan Chem, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China
[2] Collaborat Innovat Ctr Chem Sci & Engn, Tianjin 300071, Peoples R China
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2019年 / 25卷 / 12期
基金：
中国国家自然科学基金;
关键词：
coupling reactions; electron transfer; photocatalysis; ketyl radical; radical reactions; AROMATIC CARBONYL-COMPOUNDS; CATALYZED REDUCTIVE DIMERIZATION; ELECTRON-TRANSFER; PHOTOREDOX CATALYSIS; ELECTROORGANIC CHEMISTRY; DIARYL KETONES; NADH MODEL; PINACOL; ALDEHYDES; METAL;
D O I：
10.1002/chem.201804873
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Ketyl radical coupling reactions for the construction of diversely functionalized alcohols have been continuously developed for many decades. Based on the recently widespread application of photocatalysis, ketyl radical coupling reactions have also witnessed rapid development. This Minireview aims to briefly and concisely summarize the methods to construct ketyl radical intermediates through visible-light photocatalysis over the past 10years. The ketyl-radical-generation activators are grouped as Lewis acids, BrOnsted acids, in situ generated BrOnsted acids, and others.
引用
收藏
页码：2949 / 2961
页数：13
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