Conversion of carbohydrates into 5-hydroxymethylfurfural catalyzed by acidic ionic liquids in dimethyl sulfoxide

被引：54

作者：

Hu, Zhao

Liu, Bing ^{[1
]}

Zhang, Zehui

Chen, Lianqing

机构：

[1] South Cent Univ Nationalities, State Ethn Affairs Commiss, Key Lab Catalysis & Mat Sci, Wuhan 430074, Peoples R China

来源：

INDUSTRIAL CROPS AND PRODUCTS | 2013年 / 50卷

基金：

中国国家自然科学基金;

关键词：

Carbohydrates; Carboxylic acid functionalized ionic liquids; 5-Hydroxymethylfurfural; Dehydration; Alkylation; EFFICIENT CONVERSION; LANTHANIDE(III) IONS; DEHYDRATION; FRUCTOSE; CHEMICALS; CELLULOSE; SOLVENT; SYSTEM; SUGARS;

D O I：

10.1016/j.indcrop.2013.07.014

中图分类号：

S2 [农业工程];

学科分类号：

0828 ;

摘要：

An efficient process was developed for the conversion of carbohydrates into 5-hydroxymethylfurfural (HMF) using DMSO as the solvent and an acidic ionic liquid 1-carboxypropyl-3-methyl imidazolium chloride ([CMIm]Cl) as the catalyst. The effects of various reaction parameters on HMF yields were investigated. HMF yields of 95.7% and 88.4% were obtained from fructose and inulin when reactions were carried out 120 degrees C after 120 min and 180 min, respectively. The combination of ZrOCl2 and [CMIm]Cl resulted in a 50.6% yield of HMF from glucose. HMF could also be synthesized using other carbohydrates with moderate to high yields. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：264 / 269

页数：6

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