Conversion of carbohydrates into 5-hydroxymethylfurfural catalyzed by ZnCl2 in water

被引:152
|
作者
Deng, Tiansheng [1 ,3 ]
Cui, Xiaojing [1 ,2 ]
Qi, Yongqin [1 ]
Wang, Yinxiong [1 ]
Hou, Xianglin [1 ]
Zhu, Yulei [1 ,2 ]
机构
[1] Chinese Acad Sci, Inst Coal Chem, Taiyuan, Peoples R China
[2] Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan, Peoples R China
[3] Chinese Acad Sci, Grad Univ, Beijing, Peoples R China
关键词
ZINC-CHLORIDE SOLUTION; HOT COMPRESSED WATER; LIGNOCELLULOSIC BIOMASS; CHEMICALS; FRUCTOSE; GLUCOSE; CELLULOSE; TRANSFORMATION; DEHYDRATION; ACID;
D O I
10.1039/c2cc00122e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The incompletely coordinated zinc ions in the concentrated aqueous ZnCl2 solution catalyze the direct conversion of carbohydrates into 5-hydroxymethylfurfural, and a moderate HMF yield up to 50% can be achieved.
引用
收藏
页码:5494 / 5496
页数:3
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