Adsorption of linear chain molecules on carbon nanotubes

被引:13
|
作者
Alldredge, E. S. [1 ]
Badescu, S. C. [1 ]
Bajwa, N. [1 ]
Perkins, F. K. [1 ]
Snow, E. S. [1 ]
Reinecke, T. L. [1 ]
Passmore, J. L. [2 ]
Chang, Y. L. [2 ]
机构
[1] USA, Res Lab, Washington, DC 20375 USA
[2] Nanomix Inc, Emeryville, CA 94608 USA
关键词
D O I
10.1103/PhysRevB.78.161403
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We investigate molecular adsorption on single-walled carbon nanotubes (NTs) by ab initio calculations and by measurements of the conductivity response of NT arrays to trace vapors for a range of linear chain molecules. Experiment and calculations show that the short-time responses give adsorption energies that increase linearly with the molecular length. This systematic dependence indicates that the initial adsorption occurs on the defect-free regions of NTs and that these regions can play an important role in the adsorption process on NTs.
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页数:4
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