Palladium-catalyzed direct arylation of polyfluoroarenes with aryl tosylates and mesylates

被引：37
|
作者：
Lee, Dong Sheng [1 ,2 ,3 ,4 ]
Choy, Pui Ying [1 ,2 ,3 ]
So, Chau Ming [1 ,2 ,3 ]
Wang, Jun [1 ,2 ,3 ]
Lau, Chak Po [1 ,2 ,3 ]
Kwong, Fuk Yee [1 ,2 ,3 ]
机构：
[1] State Key Lab Chirosci, Shenzhen, Peoples R China
[2] PolyU Shenzhen Res Inst SZRI, Shenzhen, Peoples R China
[3] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Kowloon, Hong Kong, Peoples R China
[4] Natl Chung Hsing Univ, Dept Chem, Taichung 40227, Taiwan
来源：
RSC ADVANCES | 2012年 / 2卷 / 24期
关键词：
ELECTRON-DEFICIENT POLYFLUOROARENES; CROSS-COUPLING REACTIONS; C-H BONDS; MILD; AROMATICS; OXIDANT; ARENES; WATER;
D O I：
10.1039/c2ra21667a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This study reports the first general Pd-catalyzed direct arylation of polyfluoroarenes with aryl tosylates/mesylates. A wide range of polyfluoroarenes can be coupled with both aryl tosylates and mesylates under relatively mild reaction conditions (90 degrees C, in the presence of a weak base KOAc, without any additional acid additives). Moreover, a one-pot sequential C-H bond functionalization/C-N bond coupling has been successfully accomplished by employing one single Pd/CM-phos catalyst system.
引用
收藏
页码：9179 / 9182
页数：4
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