Synthesis and stability of thermally labile 1,2-oxaphosphetane 2-oxides and 1,2-thiaphosphetane 2-sulfides (microreview)

被引：13

作者：

Xu, Jiaxi ^{[1
]}

机构：

[1] Beijing Univ Chem Technol, Coll Chem, Dept Organ Chem, State Key Lab Chem Resource Engn, 15 Northern 3rd Ring Rd East, Beijing 100029, Peoples R China

来源：

CHEMISTRY OF HETEROCYCLIC COMPOUNDS | 2020年 / 56卷 / 08期

基金：

中国国家自然科学基金;

关键词：

RING-OPENING REACTIONS; (DIPHENYLMETHYLENE)PHENYLPHOSPHANE OXIDE; POTENT INHIBITORS; STAUDINGER; STEREOSELECTIVITY; ANNULOSELECTIVITY; STEREOCHEMISTRY; PHOSPHENES; CARBENES; INSIGHTS;

D O I：

10.1007/s10593-020-02763-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Synthesis and thermal stability of 1,2-oxaphosphetane 2-oxide and 1,2-thiaphosphetane 2-sulfide derivatives are discussed. This microreview covers the available synthetic methods of thermally labile 1,2-oxaphosphetane 2-oxides and 1,2-thiaphosphetane 2-sulfides and their fragmentation. The synthetic approaches may be classified in four distinct categories: cycloaddition, cyclization, fragmentation, and annulation.

引用

页码：979 / 981

页数：3

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