Synthesis and stability of thermally labile 1,2-oxaphosphetane 2-oxides and 1,2-thiaphosphetane 2-sulfides (microreview)

被引：13
|
作者：
Xu, Jiaxi [1 ]
机构：
[1] Beijing Univ Chem Technol, Coll Chem, Dept Organ Chem, State Key Lab Chem Resource Engn, 15 Northern 3rd Ring Rd East, Beijing 100029, Peoples R China
来源：
CHEMISTRY OF HETEROCYCLIC COMPOUNDS | 2020年 / 56卷 / 08期
基金：
中国国家自然科学基金;
关键词：
RING-OPENING REACTIONS; (DIPHENYLMETHYLENE)PHENYLPHOSPHANE OXIDE; POTENT INHIBITORS; STAUDINGER; STEREOSELECTIVITY; ANNULOSELECTIVITY; STEREOCHEMISTRY; PHOSPHENES; CARBENES; INSIGHTS;
D O I：
10.1007/s10593-020-02763-9
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Synthesis and thermal stability of 1,2-oxaphosphetane 2-oxide and 1,2-thiaphosphetane 2-sulfide derivatives are discussed. This microreview covers the available synthetic methods of thermally labile 1,2-oxaphosphetane 2-oxides and 1,2-thiaphosphetane 2-sulfides and their fragmentation. The synthetic approaches may be classified in four distinct categories: cycloaddition, cyclization, fragmentation, and annulation.
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页码：979 / 981
页数：3
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