STUDY OF THE BROMINATION OF 1,5-DINITRO-3-AZABICYCLO[3.3.1]NON-6-ENES

被引：0

作者：

Shakhkeldyan, I. V. ^{[1
]}

Atroshchenko, Yu. M. ^{[1
]}

Melekhina, N. K. ^{[1
]}

Yakunina, I. E. ^{[1
]}

Kobrakov, K. I. ^{[2
]}

Shumsky, A. N. ^{[3
]}

机构：

[1] LN Tolstoy Tula State Pedag Univ, Tula 300026, Russia

[2] AN Kosygin Moscow State Text Univ, Moscow 117419, Russia

[3] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 117913, Russia

来源：

CHEMISTRY OF HETEROCYCLIC COMPOUNDS | 2008年 / 44卷 / 06期

关键词：

3-azabicyclo[3,3,1]non-6-enes; homo- and heteronuclear correlation spectroscopy; halogenation;

D O I：

10.1007/s10593-008-0107-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The electrophilic addition of bromine to 3-substituted 1,5-dinitro-3-azabicyclo[3.3.1]non-6-ene in carbon tetrachloride is accompanied by intramolecular 3,7-cyclization with the formation of 6-bromo-3-R-1,5-dinitro-3-azonia-tricyclo[3.3.10(3,7)]nonane tribromides. In the bromination of 1,5-dinitro-3-azabicyclo[3.3.1]non-6-enes containing substituents at the double bond, molecular complexes of halogen with the substrate were obtained.

引用

页码：690 / 699

页数：10

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