STUDY OF THE BROMINATION OF 1,5-DINITRO-3-AZABICYCLO[3.3.1]NON-6-ENES

被引：0
|
作者：
Shakhkeldyan, I. V. [1 ]
Atroshchenko, Yu. M. [1 ]
Melekhina, N. K. [1 ]
Yakunina, I. E. [1 ]
Kobrakov, K. I. [2 ]
Shumsky, A. N. [3 ]
机构：
[1] LN Tolstoy Tula State Pedag Univ, Tula 300026, Russia
[2] AN Kosygin Moscow State Text Univ, Moscow 117419, Russia
[3] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 117913, Russia
来源：
CHEMISTRY OF HETEROCYCLIC COMPOUNDS | 2008年 / 44卷 / 06期
关键词：
3-azabicyclo[3,3,1]non-6-enes; homo- and heteronuclear correlation spectroscopy; halogenation;
D O I：
10.1007/s10593-008-0107-4
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The electrophilic addition of bromine to 3-substituted 1,5-dinitro-3-azabicyclo[3.3.1]non-6-ene in carbon tetrachloride is accompanied by intramolecular 3,7-cyclization with the formation of 6-bromo-3-R-1,5-dinitro-3-azonia-tricyclo[3.3.10(3,7)]nonane tribromides. In the bromination of 1,5-dinitro-3-azabicyclo[3.3.1]non-6-enes containing substituents at the double bond, molecular complexes of halogen with the substrate were obtained.
引用
收藏
页码：690 / 699
页数：10
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