Stacking transformation and defect creation in Cs intercalated TiS2 single crystals

被引：20
|
作者：
Remskar, M
Popovic, A
Starnberg, HI [1 ]
机构：
[1] Univ Gothenburg, Dept Phys, SE-41296 Gothenburg, Sweden
[2] Chalmers Univ Technol, SE-41296 Gothenburg, Sweden
[3] Jozef Stefan Inst, SI-1000 Ljubljana, Slovenia
来源：
SURFACE SCIENCE | 1999年 / 430卷 / 1-3期
关键词：
caesium; defects; intercalation; TiS2; transition metal dichalcogenides;
D O I：
10.1016/S0039-6028(99)00442-2
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The intercalation of TiS2 single crystals with Cs was studied by transmission electron microscopy. Evidence was found for an intercalation induced 1T-->3R structure transformation. The Cs+ ions formed an a root 3 x a root 3 structure. In the thinnest parts of the crystals, the intercalation induced cracks and moire fringes. In thicker parts the 1T-->3R transformation was frustrated, with formation of intercalation ribbons and dislocation loops. Air exposure resulted in de-intercalation and oxidation of Cs. The results emphasise the connections between defects and intercalation. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：199 / 205
页数：7
相关论文
共 50 条
  • [21] Morphology and Electronic Structure of Sn-Intercalated TiS2(0001) Layers
    Yuhara, Junji
    Isobe, Naoki
    Nishino, Kazuki
    Fujii, Yuya
    Lap Hong Chan
    Araidai, Masaaki
    Nakatake, Masashi
    JOURNAL OF PHYSICAL CHEMISTRY C, 2019, 123 (36): : 22293 - 22298
  • [22] OPTICAL AND ELECTRICAL-TRANSPORT STUDIES ON LITHIUM-INTERCALATED TIS2
    JULIEN, C
    SAMARAS, I
    GOROCHOV, O
    GHORAYEB, AM
    PHYSICAL REVIEW B, 1992, 45 (23): : 13390 - 13395
  • [23] Photoemission studies of the conduction band filling in Ti1.05S2 and Cs-intercalated TiS2 and ZrSe2
    Starnberg, HI
    Brauer, HE
    Hughes, HP
    JOURNAL OF PHYSICS-CONDENSED MATTER, 1996, 8 (09) : 1229 - 1234
  • [24] Selective Synthesis and Formation Mechanism of TiS2 Dendritic Crystals
    Ma, Jingjing
    Jin, Hua
    Liu, Xiaoyang
    Fleet, Michael E.
    Li, Jixue
    Cao, Xuejing
    Feng, Shouhua
    CRYSTAL GROWTH & DESIGN, 2008, 8 (12) : 4460 - 4464
  • [25] Momentum microscopy of the layered semiconductor TiS2 and Ni intercalated Ni1/3TiS2
    Suga, Shigemasa
    Tusche, Christian
    Matsushita, Yu-ichiro
    Ellguth, Martin
    Irizawa, Akinori
    Kirschner, Juergen
    NEW JOURNAL OF PHYSICS, 2015, 17
  • [26] The impact of charge transfer and structural disorder on the thermoelectric properties of cobalt intercalated TiS2
    Guelou, Gabin
    Vaqueiro, Paz
    Prado-Gonjal, Jesus
    Barbier, Tristan
    Hebert, Sylvie
    Guilmeau, Emmanuel
    Kockelmann, Winfried
    Powell, Anthony V.
    JOURNAL OF MATERIALS CHEMISTRY C, 2016, 4 (09) : 1871 - 1880
  • [27] Dielectric Mismatch Mediates Carrier Mobility in Organic-Intercalated Layered TiS2
    Wan, Chunlei
    Kodama, Yumi
    Kondo, Mami
    Sasai, Ryo
    Qian, Xin
    Gu, Xiaokun
    Koga, Kenji
    Yabuki, Kazuhisa
    Yang, Ronggui
    Koumoto, Kunihito
    NANO LETTERS, 2015, 15 (10) : 6302 - 6308
  • [28] ELECTROCHEMICAL INVESTIGATIONS OF SODIUM-INTERCALATED TIS2 USING A SOLID POLYMERIC ELECTROLYTE
    MEHROTRA, GM
    WORRELL, WL
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1983, 130 (08) : C309 - C309
  • [29] Unstable single-layered colloidal TiS2 nanodisks
    Park, Kang Hyun
    Choi, Jaewon
    Kim, Hae Jin
    Oh, Dong-Hwa
    Ahn, Joung Real
    Son, Seung Uk
    SMALL, 2008, 4 (07) : 945 - 950
  • [30] Low temperature adsorption of Cs on layered TiS2 studied by photoelectron spectroscopy
    Starnberg, HI
    Brauer, HE
    Strocov, VN
    SURFACE SCIENCE, 1997, 384 (1-3) : L785 - L790
12345